首页|原子吸收光谱法测定特医食品中钼含量的不确定度评定

原子吸收光谱法测定特医食品中钼含量的不确定度评定

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以特殊医学用途配方食品(特医食品)为检测基质,采用石墨炉原子吸收光谱技术测定其中钼含量,分析构建不确定度分量来源和不确定度评定模型,对测定的准确性和结果的可靠性进行有效评估.经分析评定,特殊医学用途配方食品中钼含量测定的主要影响因素是标准曲线拟合,次要影响因素是标准物质和样品加标回收.当样品中钼含量为0.778 mg/kg,置信度为95%时,扩展不确定度为0.096 mg/kg,测定结果表示为0.778±0.096 mg/kg(k=2).试验对食品领域钼检测方法的研究具有重要意义.
Evaluation of Uncertainty in the Determination of Molybdenum Content in Food for Special Medical Purposes by Atomic Absorption Spectroscopy
The molybdenum content in Food for Special Medical Purposes(FSMP)was determined by graphite furnace atomic absorption spectroscopy,the source of uncertainty was analyzed,the uncertainty evaluation model was established,and the accuracy of the detection and the reliability of the results were effectively evaluated.Analyzing and evaluating the experiment,the main factors affecting the determination of molybdenum content in food for special medical purposes are standard curve fitting,followed by the preparation of standard solutions and sample spiking recovery.When the molybdenum content in the sample is 0.778 mg/kg,and the confidence level is 95%,the expanded uncertainty is 0.096 mg/kg,and the determination result is expressed as 0.778±0.096 mg/kg(k=2).The experiment is of great significance to the research of molybdenum detection method in food field.

uncertaintymolybdenumFood for Special Medical Purposes

李清清、严静、刘珺瑶

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上海市质量监督检验技术研究院,国家市场监管重点实验室(乳及乳制品检测与监控技术)(上海 200233)

不确定度 特殊医学用途配方食品

上海市市场监督管理局科技项目

2023-37

2024

食品工业
上海市食品工业研究所

食品工业

影响因子:0.47
ISSN:1004-471X
年,卷(期):2024.45(6)