首页|壳聚糖溶液的流变学性质及应用研究

壳聚糖溶液的流变学性质及应用研究

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对壳聚糖稀溶液的流变学性质进行了研究,探讨了分子量和脱乙酰度结构参数以及温度、浓度、剪切速率、pH、离子强度等环境因素对壳聚糖稀溶液流变性质的影响.结果表明:壳聚糖溶液的黏度随分子量的增大而增大;随着脱乙酰度的增大和pH的增大,壳聚糖溶液的黏度先减小后增大.分别在脱乙酰度70.8%和pH4.9时黏度达到最小;离子强度的增大导致壳聚糖溶液的黏度降低.壳聚糖溶液是剪切变稀的假塑性流体,其黏度随浓度的增加逐渐增加,随温度的升高而减小,在0~80%范围内,温度对壳聚糖溶液的黏度的影响符合Arrhenius模型,活化能为32.60kJ/mol.因此当作为食品增稠剂时,应该选用高分子量、高脱乙酰度的壳聚糖,添加到酸性低盐食品体系中.
Study on rheological properties and application of chitosan solution
Rheological properties and application of chitosan solutions, in which the effects of internal factors ( molecular weight and degree of deacetylation) and external factors ( concentration, shear rate, temperature, pH and ionic strength)on viscosities of chitosan solution were studied. Results showed that viscosity increased with the increase of molecular weight and initially decreased and then increased with the increase of degree of deacetylation and pH, reached the minimum at 70.8% within the range 60.5% to 86.1% and at pH 4.9 between 3.9 and 5.9 respectively. Viscosities of chitosan solution decreased with the increase of ionic strength excessively.Furthermore,chitosan solution exhibited shear thinning behavior following the power law model. Viscosity increased with the increase of concentration, and decreased with the increase of temperature. The decrease in viscosity (within 0~80℃)followed an Arrhenius temperature dependence, and the activation energy was 32.60kJ/mol. As food thickener, it is suitable to choose chitosan with higher molecular weight and higher degree of deacetylation and add into the acidic food systems containing low salt.

李星科、姜启兴、夏文水

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江南大学食品科学与技术国家重点实验室,江苏无锡214122

江南大学食品学院,江苏无锡214122

壳聚糖溶液 黏度 流变性质 应用

国家高技术研究发展计划(863计划)食品科学与技术国家重点实验室目标导向项目江苏省科技成果转化项目

2007AA100401SKLF-MB-200805BA2009082

2011

食品工业科技
北京一轻研究院

食品工业科技

CSTPCDCSCD北大核心
影响因子:0.842
ISSN:1002-0306
年,卷(期):2011.32(2)
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