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不同发酵时间的郫县豆瓣酱挥发性成分分析

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为研究不同发酵时间对郫县豆瓣酱挥发性成分的影响,采用顶空固相微萃取(HS-SPME)结合气质联用技术(GC-MS),对两种原料生椒醅与阴瓣子,以及3种不同发酵时间的郫县豆瓣酱中的挥发性成分进行分析鉴定.从两种原料中共分离鉴定出66种挥发性化合物,其巾醇5种、酯24种、酸2种、醛5种、烃23种、酚4种、呋喃化合物1种、含氮化合物2种;从3种发酵豆瓣中共分离鉴定出88种挥发性化合物,其中醇7种、酯20种、酸3种、醛9种、烃35种、酚6种、酮4种、含氮化合物3种.其相同的成分是苯甲醛、苯乙醛、(Z)-3,7-二甲基-1,3,6-辛三烯、3,7-二甲基-1,6-辛二烯-3-醇、2,6,6-三甲基-2-环己烯-1,4-二酮、4-乙基愈创木酚、十四烷、十七烷、十六酸乙酯等.
Analysis of Volatile Composition of Pixian Bean Sauces with Different Fermentation Time
With the aim to understand the effect of fermentation time on volatile composition of Pixian bean sauce,two raw materials,namely fermented chili and raw beans,and Pixian bean sauces fermented for 3,1 years or 3 months were analyzed for volatile composition by headspace solid-phase microextraction(HS-SPME)coupled to GC-MS.Added together,66 compounds were identified in both materials of Pixian bean sauce,including alcohols(5),esters(24),acids(2),aldehydes(5),hydrocarbons(23),phenols(4),furans(1),and nitrogen-containing compounds(2).Added together,88 compounds were identified in Pixian bean sauces with different fermentation time,including alcohols(7),esters(20),acids(3),aldehydes(9),hydrocarbons(35),phenols(6),ketones(4),and nitrogen-containing compounds(3).The compounds simultaneously found in the above 5 samples were benzaldehyde,benzeneacetaldehyde,(Z)-3,7-dimethyl-1,3,6-octatriene,3,7-dimethyl-1,6-octadien3-ol,2,6,6-trimethyl-2-cyclohexene-1,4-dione,4-ethylguaiacol,ethyl hexadecanoate,and so on.These results can offer valuable reference for the study of fermentation process and flavoring preparation of Pixian bean sauce.

Pixian bean saucevolatile composition:solid phase micro-extraction(SPME)gas chromatography-massspectrometry(GC-MS)

张玉玉、孙宝国、冯军、黄明泉

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北京工商大学化学与环境工程学院,北京,100048

上虞市环境保护局,浙江,上虞,312300

郫县豆瓣酱 顶空固相微萃取 气相色谱-质谱法 挥发性成分

北京市高层次人才项目

PXM2009-014213-073687

2010

食品科学
北京食品科学研究院

食品科学

CSTPCDCSCD北大核心
影响因子:1.327
ISSN:1002-6630
年,卷(期):2010.31(4)
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