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低温风干型酱鸭加工过程中脂质氧化特性

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为研究酱鸭加工过程中脂质氧化特性,在传统酱鸭加工工艺的基础上,引入低温风干工艺制备酱鸭,并分析其加工过程中pH值、磷脂、游离脂肪酸(free fatty acid,FFA)、过氧化值(peroxide values,POV)、硫代巴比妥酸(thiobarbituric acid reactive substances,TBARS)值和挥发性盐基氮(total volatile base nitrogen,TVB-N)值的变化.结果表明:pH值从原料肉的5.81升高至杀菌肉的6.09;酱鸭加工过程中肌内磷脂的分子种类结果表明,脑磷脂(phosphatidylethanolamine,PE)有5 种分子含量较高,分别是PE(C16:0/C20:4)、PE(C16:0/C18:1)、PE (C16:0/C22:5)、PE(C16:0/C22:4)和PE(C16:0/C22:6);POV和TBARS值均先升高后下降;TVB-N值在腌制、酱制和杀菌阶段显著降低,而风干使其升高(P<0.05).相关性结果表明,总FFA与单不饱和脂肪酸(R=0.92,P<0.01),多不饱和脂肪酸与pH值(R=0.90,P<0.01),多不饱和脂肪酸与TBARS值(R=0.80,P<0.01),TBARS值与POV(R=0.89,P<0.01),POV与TVB-N值(R=0.81,P<0.01)均呈高度正相关,卵磷脂与PE呈显著负相关(R=-1.00,P<0.01).本研究为低温风干工艺下酱鸭的脂质分解氧化机理研究提供理论依据.
Characteristics of Lipid Oxidation during Processing of Low-Temperature Air-Dried Sauced Duck
This study aimed to examine the characteristics of lipid oxidation during sauced duck processing. Low-temperature air drying was introduced to the processing of traditional sauced duck. Changes in pH, phospholipids, free fatty acid (FFA), peroxide values (POV), thiobarbituric acid reactive substances (TBARS) and total volatile base nitrogen (TVB-N) values were investigated during processing. The results showed that the pH value of raw duck meat increased from 5.81 to 6.09 after sterilization. Analysis of the intramuscular phospholipid composition indicated that C16:0/C20:4, C16:0/C18:1, C16:0/C22:5, C16:0/C22:4and C16:0/C22:6were the primary phosphatidylethanolamines (PE). Both POV and TBARS values increased firstly and then decreased. TVB-N values significantly decreased during salting, marination and sterilization, but increased during air-drying significantly (P < 0.05). Total FFA showed a significantly positive correlation with monounsaturated fatty acids (MUFA) (R = 0.92, P < 0.01), and we also found a significantly positive correlation between PUFA and pH values (R = 0.90, P < 0.01), between PUFA and TBARS values (R = 0.80, P < 0.01), between TBARS and POV (R = 0.89, P< 0.01), and between POV and TVB-N values (R = 0.81, P < 0.01), but phosphatidylcholine (PC) was significantly negatively correlated with PE (R = ?1.00, P < 0.01). These results may provide a theoretical basis for understanding the mechanism of lipid oxidation during the processing of low-temperature air-dried sauced duck.

low-temperature air-dryingsauced duckfree fatty acid (FFA)phospholipidlipid oxidation

程珂萌、周昌瑜、潘道东、曹锦轩、曾小群、孙杨赢、吴振

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宁波大学 浙江省动物蛋白食品精深加工技术重点实验室,浙江 宁波 315211

南京师范大学金陵女子学院食品科学与营养系,江苏 南京 210097

低温风干 酱鸭 游离脂肪酸 磷脂 脂质氧化

现代农业产业技术体系建设专项宁波市科技富民项目

CARS-42-252017C10038

2018

食品科学
北京食品科学研究院

食品科学

CSTPCDCSCD北大核心EI
影响因子:1.327
ISSN:1002-6630
年,卷(期):2018.39(12)
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