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海带泡菜货架期质构品质的钠钙比调控机制

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为明确海带泡菜货架期质构品质的钠钙比调控机制,以期为外源性钙盐改善货架期海带泡菜的质构品质提供理论指导.研究体系发酵酸度及钠钙比对海带泡菜低温(4℃)货架期质构品质的影响,并解析货架期海带凝胶水分分布及钙盐桥结构的演替变化.结果表明,海带泡菜的硬度随着发酵酸度的升高呈现下降趋势,而乳酸钙有效减缓了海带泡菜的硬度变化,当体系钠钙比为1.5∶1时,海带泡菜经低温货架6个月的硬度保持率相比对照组提高了92.8%.扫描电子显微镜观察与低频氢谱核磁共振分析结果显示,乳酸钙减轻了发酵酸引起的海带组织形态破坏,抑制了货架期细胞束缚水向自由水迁移.当体系钠钙比为2∶1时,海带泡菜货架6个月后的自由水比例仅增加10.29个百分点;钙离子光电子能谱分析结果显示,乳酸钙强化海带泡菜货架期质构品质的作用机制可能与体系钠钙比于2∶1或1.5∶1条件下形成稳定的钙盐桥结构有关.
Regulatory Mechanism of Sodium/Calcium Ratio on Texture Quality of Kelp Pickle during Shelf-Life Period
This work aims to study the regulatory mechanism of calcium、fortification on the texture of kelp pickle during the shelf-life period in order to provide theoretical support for improving its texture quality using exogenous calcium.The effects of fermentation acidity and sodium/calcium ratio on the texture of kelp pickle during its shelf life at 4 ℃ were studied,and the evolution of water distribution and the structure of calcium ion bridge was analyzed.The results showed the hardness of kelp pickle decreased with increasing fermentation acidity,but its changes were effectively slowed down by exogenous calcium lactate.The rate of hardness preservation of kelp pickle with a sodium/calcium of 1.5∶1 increased by 92.8%compared with the control group.The results of scanning electron microscopy(SEM)and low-frequency nuclear magnetic resonance(NMR)spectroscopy showed calcium lactate alleviated the morphological damage of kelp tissues caused by acid produced during fermentation,and inhibited the transition of bound water to free water during the shelf-life period.The proportion of free water in kelp pickle with a sodium/calcium ratio of 2∶1 increased by only 10.29 percentage points after six months of storage.The results of X-ray photoelectron spectroscopy(XPS)showed that the mechanism by which calcium lactate enhanced the texture of kelp pickle during its shelf-life might be related to the formation of a stable calcium ion bridge at a sodium/calcium ratio of 2∶1 or 1.5∶1.

kelpmicrobial fermentationcalcium lactatetexture propertiescalcium bridge structure

陈秉彦、林晓姿、李维新、窦芳娇、何志刚

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福建省农业科学院农业工程技术研究所,福建福州 350002

农业农村部亚热带特色果蔬菌加工重点实验室(部省共建),福建福州 350002

福建省农产品(食品)加工重点实验室,福建福州 350002

海带 微生物发酵 乳酸钙 质构品质 钙盐桥结构

福建省农科院自由探索科技创新项目福建省农科院科技创新团队建设项目

ZYTS202222CXTD2021016-1

2023

食品科学
北京食品科学研究院

食品科学

CSTPCDCSCD北大核心
影响因子:1.327
ISSN:1002-6630
年,卷(期):2023.44(23)
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