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轻度盐腌大黄鱼的气味特征及形成途径

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以大宗养殖海水鱼——冰鲜大黄鱼和轻度盐腌大黄鱼为对象,通过固相微萃取(solid phase microextraction,SPME)结合气相色谱-质谱(gas chromatography-mass spectrometry,GC-MS)联用、气相色谱-嗅闻(gas chromatography-olfactometry,GC-O)检测和气味强度值(odor activity value,OAV)分析,研究轻度盐腌对大黄鱼风味的影响.GC-MS分析表明,冰鲜大黄鱼和轻度盐腌大黄鱼中正己醛、壬醛、庚醛、1-辛烯-3-醇、茴香脑和正己醇含量高于其他挥发性化合物.GC-O和OAV分析表明,冰鲜大黄鱼中1-辛烯-3-醇、正辛醛、壬醛、正己醛、庚醛、(E,Z)-2,6-壬二烯醛、反-2-辛烯醛和茴香脑对风味有较大的影响(OAV>1);轻度盐腌大黄鱼中芳樟醇、壬醛、正己醛、正辛醛、1-辛烯-3-醇、茴香脑、(E,Z)-2,6-壬二烯醛和庚醛对风味有较大影响(OAV>1).轻度盐腌后风味变化的原因是芳樟醇的OAV显著增加,以及1-辛烯-3-醇、正己醛、壬醛和正辛醛OAV显著降低.相关风味成分的变化可能和不饱和脂肪酸氧化降解、萜类的生物合成、芳香醇异构化、脂肪醛氧化及还原、酯化等反应相关.
Odor Characteristics and Formation Pathways of Low-Salted Large Yellow Croaker
In this study,our purpose was to investigate the effect of mild salting on the flavor of large yellow croaker.The volatile flavor compounds of raw(unsalted)and low-salted large yellow croaker were determined by solid phase microextraction(SPME)combined with gas chromatography-mass spectrometry(GC-MS)and evaluated by gas chromatography-olfactometry(GC-O)and odor activity values(OAV)analysis.The GC-MS analysis showed that the contents of hexanal,nonanal,heptanal,1-octene-3-ol,anethole and hexanol in both samples were higher than those of other volatile compounds identified.GC-O and OAV analysis showed that the flavor of raw large yellow croaker was significantly affected by 1-octene-3-ol,octanal,nonanal,hexanal,heptanal,(E,Z)-2,6-nonadienal,trans-2-octenal and anethole(OAV>1);the flavor of low-salted large yellow croaker was significantly affected by linalool,nonanal,hexanal,octanal,1-octene-3-ol,anethole,(E,Z)-2,6-nonadienal and heptanal(OAV>1).The changes in flavor after salting treatment was attributed to a significant increase in the OAV of linalool and anethole,and a significant decrease in the OAV of 1-octene-3-ol,hexanal,nonanal,trans-2-octenal,(E,Z)-2,6-nonadienal,heptanal and octanal.The changes of some flavor components might be related to reactions such as the oxidative degradation of unsaturated fatty acids,the biosynthesis of terpenoids,the isomerization of aromatic alcohols,the oxidation and reduction of aliphatic aldehyde and esterification.

large yellow croakerlow-saltedgas chromatography-mass spectrometrycharacteristic aroma componentsreaction pathway

关君兰、姚雨萱、伍菱、王永兴、沈细冰、杜希萍、倪辉

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集美大学海洋食品与生物工程学院,福建厦门 361021

大连工业大学海洋食品精深加工关键技术省部共建协同创新中心,辽宁大连 116034

福建省食品微生物与酶工程重点实验室,福建厦门 361021

漳州市科技情报研究所,福建漳州 363000

厦门市食品与生物工程与技术研究中心,福建厦门 361021

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大黄鱼 轻度盐腌 气相色谱-质谱联用 特征香气成分 反应途径

国家重点研发计划重点专项(十三五)

2018YFD0901003

2023

食品科学
北京食品科学研究院

食品科学

CSTPCDCSCD北大核心
影响因子:1.327
ISSN:1002-6630
年,卷(期):2023.44(24)
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