首页|便携式重金属电化学传感器研制及其在大米重金属检测中的应用

便携式重金属电化学传感器研制及其在大米重金属检测中的应用

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[目的]建立大米中Cd2+和Pb2+的电化学快速检测方法.[方法]采用一次性丝网印刷电极,基于阳极溶出伏安法,建立了基于同位镀铋电极的便携式电化学传感器.[结果]通过方波伏安法(SWV)、循环伏安法(CV)、计时电流法(I-T)对传感器进行了优化,在最适检测条件下,Cd2+的线性范围为20~80 μg/L,Pb2+的线性范围为10~80 μg/L,Cd2+的检测限为 1.201 0 μg/L,Pb2+的检测限为0.963 9 μg/L.[结论]建立的重金属电化学传感器灵敏度高,操作简单、快速、绿色环保.
Development of portable electrochemical sensor for heavy metals and application of detection of heavy metals lead and cadmium in rice
[Objective]To develop an efficient electrochemical method for the rapid detection of cadmium and lead ions(Cd2+and Pb2+)in rice samples.[Methods]Designed a portable electrochemical sensor utilizing a disposable screen printed electrode and anodic stripping voltammetry with an isoplated bismuth electrode.This setup was further optimized through square wave voltammetry(SWV),cyclic voltammetry(CV),and chronocurrent methods(I-T).[Results]The proposed approach exhibited outstanding performance with a linear detection range of 20 to 80 μg/L for Cd2+and 10 to 80 μg/L for Pb2+.The LOD of the cadmium ion were 1.201 0 μg/L,the LOD of the lead ion were 0.963 9 μg/L.[Conclusion]Our newly established electrochemical sensor for heavy metal detection in rice offers high sensitivity,ease of operation,rapid analysis,and aligns with environmentally friendly practices.

ricesheavy metal residuescreen printed electrodeelectrochemical detection

徐昊阳、王冉冉、姚帮本、陈伟、邓尚贵、姚丽

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浙江海洋大学食品与药学学院,浙江舟山 316022

合肥工业大学食品与生物工程学院,安徽 合肥 230601

安徽省产品质量监督检验研究院,安徽合肥 230051

长沙理工大学食品与生物工程学院,湖南长沙 410114

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大米 重金属残留 丝网印刷电极 电化学检测

安徽省自然科学基金项目国家重点研发计划项目安徽省重点研究与开发计划项目

2208085QB562022YFF11029002022f04020003

2024

食品与机械
长沙理工大学

食品与机械

CSTPCD北大核心
影响因子:0.89
ISSN:1003-5788
年,卷(期):2024.40(7)
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