首页|玉米醇溶蛋白-果胶复合纳米颗粒的制备及其在稳定Pickering乳液中的应用

玉米醇溶蛋白-果胶复合纳米颗粒的制备及其在稳定Pickering乳液中的应用

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基于玉米醇溶蛋白与果胶之间的相互作用,利用抗性溶剂沉淀法制备不同甲氧基果胶与玉米醇溶蛋白的复合纳米颗粒,并对其乳化性质进行研究.结果表明,相比于纯玉米醇溶蛋白颗粒,复合纳米颗粒具有纳米尺度、均一的颗粒结构、优良的乳化能力,作为乳化剂颗粒可以形成稳定的Pickering乳液.研究结果表明,果胶的酯化度对于复合纳米颗粒乳化能力具有重要影响,可以对玉米醇溶蛋白表面疏水性进行较好的调控,所形成的复合纳米颗粒三相接触角接近 90°.高甲氧基果胶与玉米醇溶蛋白所形成的复合纳米颗粒稳定的Pickering乳液具有更小的乳液粒径,在乳液液滴表面分布更均匀,且对于外界环境pH值的变化具有更好抗性.综上,玉米醇溶蛋白与果胶所形成的复合纳米颗粒可以作为生物基Pickeirng乳液乳化剂颗粒,其中高甲氧基果胶为更好的选择.
Preparation of Zein-Pectin Composite Nanoparticles and Their Application in Stabilizing Pickering Emulsion
Based on the interaction between zein and pectin,composite nanoparticles of different methoxyl pectins and zein were prepared using the anti-solvent precipitation method,and their emulsification properties were investigated.The results showed that compared with pure zein particles,the composite nanoparticles had a nano-scale,uniform particle structure and an excellent emulsifying capacity.As emulsifier particles,they could form stable Pickering emulsions.The study also demonstrated that the degree of methoxylation of pectin had a significant influence on the emulsifying capacity of the composite nanoparticles,allowing for an effective modulation of the hydrophobicity of the zein surface and thus resulting in composite nanoparticles with a three-phase contact angle close to 90°.Furthermore,the Pickering emulsions stabilized by the composite nanopar-ticles of high methoxyl pectin and zein exhibited smaller emulsion particle sizes,a more uniform distribution of the composite nanoparticles on the surface of emulsion droplets,and better resistance to external pH changes.Experimental results confirmed that the composite nanoparticles formed by zein and pectin could serve as bio-based emulsifier particles for Pickering emulsions,with high methoxyl pectin being the preferred choice.

zeinpectinnanoparticlewettabilityPickering emulsion

李文慧、刘媛媛、姜金池、龙淑媛、杨文革、胡永红

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南京工业大学食品与轻工学院,江苏 南京 211816

玉米醇溶蛋白 果胶 纳米颗粒 润湿性 Pickering乳液

2025

食品研究与开发
天津市食品研究所,天津市食品工业生产力促进中心

食品研究与开发

影响因子:0.561
ISSN:1005-6521
年,卷(期):2025.46(1)