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两种不同尺寸石墨材料制备改性石墨烯前基体的性能研究

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石墨由于在新能源、信息技术等国民经济先导性产业和高端制造产业的广泛应用,得到越来越多的关注.选用两种颗粒度不同的典型石墨为原材料,经过物理表征后发现,两种典型石墨的比表面积相差无几,但其孔径差别比较大,两种典型石墨的孔径分别为5.8 nm和1.2 nm;采用改性的Hummers方法制备的前基体1-氧化石墨烯(1-GO)和2-氧化石墨烯(2-GO),对制备的1-GO和2-GO前基体进行物理表征,虽然两种GO前基体表面都已经嵌入了含氧官能团并呈现单层结构,在后续阶段以2-GO为基体制备的石墨烯相关基体与其它材料进行复合时却表现出明显不同的性能.
Study on the Properties of Modified Graphene Precursors Prepared from Two Different Sized Graphite Materials
Graphite has received more and more attention due to its extensive application in new energy,infor-mation technology and other leading industries of the national economy and high-end manufacturing industries.Two types of typical graphite with different particle sizes are selected as raw materials.After physical characterization,it is found that the specific surface area of the two types of typical graphite is almost the same,but their pore diame-ters are quite different.The pore diameters of the two types of typical graphite are 5.8nm and 1.2nm respectively.Then,1-GO and 2-GO are prepared using the modified Hummers method based on the two types of typical graphite,and the prepared 1-GO and 2-GO matrices are physically characterized,Although the surfaces of the two pre GO matrices have been embedded with oxygen containing functional groups and present a monolayer struc-ture,graphene related matrices prepared with 2-GO as the matrix in the subsequent stage show significantly differ-ent properties when compounded with other materials.

graphitegraphenenitrogen doping

陈玉华

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商丘职业技术学院交通学院,河南商丘 476100

石墨 石墨烯 氮掺杂

2024

商丘职业技术学院学报
商丘职业技术学院

商丘职业技术学院学报

影响因子:0.18
ISSN:1671-8127
年,卷(期):2024.23(5)