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草木灰对矿区重金属复合污染土壤的修复效果研究

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选取草木灰为稳定化材料,对矿区重金属复合污染土壤进行修复试验,研究不同处理条件下重金属有效态含量、形态分布和土壤理化性质的变化,并结合相关性分析对修复机制进行探讨。研究结果表明:草木灰能有效降低矿区污染土壤中Pb、Zn、Cd的有效态含量,促进土壤中Pb、Zn、Cd由不稳定形态转换为稳定形态,显著提高土壤pH值和阳离子交换量。在草木灰用量为 4%、修复时间为 10 d的最佳处理条件下,Pb、Zn、Cd的稳定化率分别为 55。31%、60。78%、39。56%,土壤pH值为 7。53,阳离子交换量为 17。98 cmol/kg;重金属稳定化率与土壤pH值和阳离子交换量呈显著正相关;草木灰对重金属复合污染土壤的修复机制主要为静电吸附和化学沉淀。研究成果可为矿区重金属污染土壤修复实践提供理论依据。
Study on the Remediation Effect of Plant Ash on Multiple Heavy Metal Contaminated Soil in Mining Area
The plant ash was selected as a stabilizing material to remediate the multiple heavy metal contaminated soil in mining area.The changes of heavy metal available content,speciation distribution and soil physicochemical properties under the treatment of adding different amounts of plant ash were investigated,and the remediation mechanism was discussed in combination with correlation analysis.The results showed that the plant ash could effectively reduce the available content of Pb,Zn and Cd in the contaminated soil of the mining area,promote the transformation of Pb,Zn and Cd from unstable forms to stable forms,and significantly increase the soil pH and cation exchange capacity.Under the optimal condition of 4%plant ash and 10 d remediation time,the stabilization efficiencies of Pb,Zn and Cd achieved 55.31%,60.78%and 39.56%respectively,with a soil pH of 7.53 and a cation exchange capacity of 17.98 cmol/kg.There was a significant positive correlation between heavy metal stabilization efficiency and soil pH as well as cation exchange capacity.The remediation mechanisms of plant ash on multiple heavy metal contaminated soil mainly include electrostatic adsorption and chemical precipitation.The research results can provide theoretical basis for the remediation practice of heavy metal contaminated soil in mining area.

plant ashheavy metalstabilizationremediation

林星杰、张鸽、苗雨、张弛、谭海伟、李昉泽、庞治坤、信心

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矿冶科技集团有限公司,北京 100160

草木灰 重金属 稳定化 修复

2024

环境影响评价
重庆市环境科学研究院

环境影响评价

影响因子:0.66
ISSN:2095-6444
年,卷(期):2024.46(6)