首页|自来水厂不同水处理工艺环节对全氟化合物浓度的影响

自来水厂不同水处理工艺环节对全氟化合物浓度的影响

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全氟化合物(perfluoroalkyl substances,PFASs)是一类具有毒性、积累性、持久性等特性的新型污染物.本文采集了成都某自来水厂水源水、末梢水以及不同工艺环节的水样进行分析,研究不同处理工艺对去除PFASs的影响.结果表明,在水源水、自来水厂各工艺段水以及末梢水中,全氟辛烷羧酸(perfluorooctanoic acid,PFOA)的含量最高,其次是全氟丁酸(perfluorobutanoic acid,PFBA),分别占12种全氟化合物的总浓度(Σ12PFASs)的26.7%~74.1%和12.0%~26.0%,说明PFOA和PFBA是主要污染物.经过水厂处理后,Σ12PFASs从水源水的2.22 ng/L下降到了出厂水的1.74 ng/L,下降了21.6%,说明自来水厂对PFASs的去除有一定效果.在自来水厂各处理环节中,折板反应池的Σ12PFASs浓度最高,为4.42 ng/L,其中PFOA的占比最高.混凝对PFASs的去除效果最为明显,去除率达到48.9%,说明在常规处理工艺中混凝对PFASs的去除起到重要作用.该自来水厂出水中的PFOA和全氟辛烷磺酸(perfluorooctane sulfonic acid,PFOS)的浓度远低于《生活饮用水卫生标准》(GB 5749-2022)的限值,符合日常安全用水要求.
Influence of Different Water Treatment Processes on the Concentration of Perfluoroalkyl Substances in Waterworks
Perfluoroalkyl substances(PFASs)are a new type of pollutants with toxic,accumulative and persistent properties.This pa-per collected and analyzed water samples from the source water,end water and different process steps of a tap water treatment plant in Chengdu to study the effects of treatment processes on the removal of PFASs.The results show that Perfluorooctanoic acid(PFOA)has the highest concentration in all samples,followed by perfluorobutanoic acid(PFBA),accounting for 26.7%~74.1%and 12.0%~26.0%,respectively,suggesting that PFOA and PFBA are the main PFASs.After the treatment,the total concentrations of twelve PFASs decreased from 2.22 ng/L(source water)to 1.74 ng/L(end water),with the removal rate of 21.6%.The result indi-cated that the tap water treatment plant is effective in the removal of PFASs.The highest concentration of Σ12PFASs(4.42 ng/L)occurred at the folded plate reactor,and PFOA accounted for the highest proportion.Coagulation displayed the greatest removal effi-ciency of PFASs,with a removal rate of 48.9%.The concentrations of PFOA and(perfluorooctane sulfonic acid,PFOS)in the final water of this treatment plant are far below the limit values of the"Standards for Drinking Water Quality"(GB 5747-2022),so it can and meet the requirements of daily water safety.

perfluoroalkyl substances(PFASs)tap water treatment processtap waterremoval efficiency

雷梦真、方淑红、王若男

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成都信息工程大学 资源环境学院,成都 610225

四川省生态环境监测总站,成都 610074

全氟化合物 水处理工艺 自来水 去除率

国家自然科学基金四川省科技计划四川省科技计划

216070182021YJ03842022JDR0309

2024

三峡生态环境监测
中华预防医学会,国家食品安全风险评估中心

三峡生态环境监测

ISSN:
年,卷(期):2024.9(1)
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