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安庆市挥发性有机物污染特征及来源解析

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基于2022年1-12月安庆市挥发性有机物(volatile organic compounds,VOCs)在线监测数据,分析了VOCs污染特征及来源解析.结果显示:2022年安庆市VOCs的体积浓度均值为(18.2±8.77)×10-9,各类VOCs组分浓度占比排序为烷烃(61.0%)>芳香烃(15.9%)>烯烃(14.5%)>炔烃(8.6%),臭氧季VOCs体积浓度均值为(16.3±8.32)×10-9,非臭氧季VOCs体积浓度比臭氧季高25.2%,与臭氧季高温和强紫外辐射有关.VOCs的体积浓度分布总体呈现夏季低、冬季高的特征,小时浓度则呈现早晚双峰变化规律.臭氧季和非臭氧季臭氧生成潜势(ozone formation potential,OFP)排名前10的物质相似,主要包括甲苯、间/对二甲苯、乙烯、异戊烷、丙烯、邻二甲苯等,芳香烃及烯烃是安庆市臭氧管控的关键组分.根据正交矩阵因子模型(positive matrix factorization,PMF)源解析结果,安庆市环境空气中VOCs来源由高到低依次为机动车排放源(28.22%)、工业源(22.89%)、液化石油气/天然气源(19.15%)、溶剂涂料源(16.26%)和天然源(13.48%).机动车排放源和工业源是安庆市环境空气中VOCs的主要来源,建议加强对安庆市机动车尾气及工业排放的管控.
Pollution Characteristics and Source Apportionment of Volatile Organic Compounds in Anqing
Based on the online monitoring data of volatile organic compounds(VOCs)in Anqing from January to December 2022,this paper analyzed the pollution characteristics and source apportionment of VOCs.The results show that the average volume con-centration of VOCs in 2022 of Anqing was(18.2±8.77)×10-9,and the concentration proportion of various VOCs components was ranked as alkane(61.0%)>aromatic hydrocarbons(15.9%)>alkene(14.5%)>alkyne(8.6%);the mean volume concentration of VOCs in the ozone season was(16.3±8.32)×10-9;the VOCs volume concentration in the non-ozone season was 25.2%higher than that in the ozone season,which is related to the high temperature and strong ultraviolet radiation in the ozone season.The volume concen-tration distribution of VOCs was generally low in summer and high in winter,while the hourly bimodal changes in the morning and evening.The top 10 species of ozone formation potential(OFP)in ozone and non-ozone seasons were similar,mainly including tolu-ene,m,p-xylene,ethylene,i-pentane,propylene,o-xylene,etc.Aromatic hydrocarbons and alkene were the key components of O3 control in Anqing City.According to the PMF source analysis results,the VOCs source in the ambient air in Anqing are the motor vehicle emission sources(28.22%),industrial sources(22.89%),liquefied petroleum gas/natural gas(19.15%),solvents and coating sources(16.26%)and natural sources(13.48%)sorted from highest to lowest.The motor vehicle emission sources and industrial sources were the main sources of VOCs in the ambient air of Anqing,so it suggested to strengthen the control of motor vehicle exhaust gas and industrial emissions in Anqing City.

volatile organic compounds(VOCs)pollution characteristicssource apportionmentAnqing

章宜洁、潘玉锁、魏太平

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安徽省安庆生态环境监测中心,安徽 安庆 246003

安徽蓝盾光电子股份有限公司,安徽 铜陵 244000

挥发性有机物 污染特征 来源解析 安庆市

安庆市打赢蓝天攻坚战技术保障服务项目

AQZB-2019-0514

2024

三峡生态环境监测
中华预防医学会,国家食品安全风险评估中心

三峡生态环境监测

ISSN:
年,卷(期):2024.9(1)
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