首页|1-丁烯/聚1-丁烯溶液体系黏度的测量及建模

1-丁烯/聚1-丁烯溶液体系黏度的测量及建模

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测定了1-丁烯/聚1-丁烯溶液体系在不同的固含率(C,%(w))、温度(t,℃)和剪切速率(γ,s-1)下的黏度(η,Pa·s),并对测定的黏度数据进行拟合.实验结果表明,1-丁烯/聚1-丁烯溶液体系的黏度随温度的升高而降低,随剪切速率的增大而降低,随固含率的增大而增大.在10s-1<γ<500s-、70℃≤t≤130℃、2.5%≤C≤25.0%的条件下,将1-丁烯/聚1-丁烯溶液体系测定的黏度数据经拟合得到恒压黏度模型:η=2.543×10-4y-0.3611×exp[1 625.53/(t+ 273)]×exp(12.76C).该黏度模型的方差齐性检验值为17 314.02、结果可信度值为0、调整相关系数平方为0.946 8,对实验数据拟合较好.
Measurement and Modeling of Butene-1/Polybutylene-1 Solution Viscosity
The viscosity (η) of butane-1/polybutylene-1 solutions with different solid content (C) at different temperature (t) and shear rate (γ) was measured and a viscosity model was established.The results indicated that the viscosity of the butane-1/polybutylene-1 solutions decreased with temperature rise,decreased with increasing shear rate and increased with increasing solid content.Under the condition of 10 S-1 < γ < 500 S-1,70 ℃ ≤t≤ 130 ℃ and 2.5%≤ C≤25%,the constant pressure viscosity model for the butane-1/polybutylene-1 solutions was η =2.543 × 10-4y-0.3611 × exp [1 625.53/(t + 273)] × exp(12.76C) with homoscedasticity test value of 17 314.02,confidence level of 0 and correlation coefficient square of 0.946 8.

polybutylene-11-buteneviscosity model

沈周峰、王金刚、于鲁强、陈江波、毕福勇、杜亚锋

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中国石化 北京化工研究院,北京100013

聚1-丁烯 1-丁烯 黏度模型

2014

石油化工
中国石化集团资产经营管理有限公司 北京化工研究院 中国化工学会石油化工专业委员会

石油化工

CSTPCDCSCD北大核心
影响因子:0.916
ISSN:1000-8144
年,卷(期):2014.43(12)
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