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基于聚乙烯微孔膜的超滤膜制备与性能

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超滤膜能有效截留料液中的蛋白质、病毒、酶等大分子物质,在生物制药、食品工业、污水处理与资源化利用等行业有广泛的应用。为解决传统聚酯无纺布-亲水聚合物复合超滤膜成本昂贵、工艺复杂、国产化率不高的问题,探索以聚烯烃为原料制备超滤膜的潜在方法,通过乙烯-乙烯醇共聚物(EVOH)亲水改性和涂覆聚乙烯醇(PVA)开发了一种基于商品聚乙烯微孔膜的超滤膜。考察了亲水改性条件、PVA交联时间、PVA溶液含量对超滤膜性能的影响。实验结果表明,以 0。30%(w)的EVOH改性 360 min的聚乙烯微孔膜为基膜,PVA含量为 2。5%(w)、交联时间为 5 min时制备的超滤膜性能最佳;该超滤膜对1 g/L牛血清白蛋白水溶液具有86。96 L/(m2·h·MPa)的渗透通量,同时牛血清白蛋白的截留率可达98。63%。
Preparation and properties of ultrafiltration membrane based on polyethylene microporous film
Ultrafiltration(UF)membranes are widely used in biomedical engineering,food industry,and sewage treatment and reuse because they exhibit efficient rejection to macromolecules such as proteins,viruses,and enzymes in the feed liquid.Traditional composite UF membranes are composed of polyester non-woven cloths and hydrophilic polymers,which are expensive and have complicated processes and low import substitution rates.To explore a novel idea of preparing UF membranes by using polyolefin,a UF membrane based on commercial polyethylene microporous film was prepared by ethylene-vinyl alcohol copolymer(EVOH)hydrophilic modification and polyvinyl alcohol(PVA)coating.The effects of hydrophilic modification conditions,PVA crosslinking time and PVA solution content on the performance of UF membranes were investigated.The experimental results show that the UF membrane prepared with 0.30%(w)EVOH modified polyethylene microporous membrane for 360 min as the base membrane,PVA content of 2.5%(w)and crosslinking time of 5 min has the best performance.The experimental results show that the UF membrane has a permeation flux of 86.96 L/(m2·h·MPa)for 1 g/L bovine serum slbumin(BSA)solution,and the rejection can reach 98.63%.

membrane separationultrafiltration membranepolyethylenehydrophilic modificationpolyvinyl alcohol

钟天、赵国珂、张杨、潘国元、李煜、刘轶群

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中石化(北京)化工研究院有限公司,北京 100013

膜分离 超滤膜 聚乙烯 亲水改性 聚乙烯醇

2025

石油化工
中国石化集团资产经营管理有限公司 北京化工研究院 中国化工学会石油化工专业委员会

石油化工

北大核心
影响因子:0.916
ISSN:1000-8144
年,卷(期):2025.54(1)