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特殊润湿性材料分离乳液的影响因素

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自主研发了特殊润湿性不锈钢筛网,分别考察了温度、过滤压力、pH、水油比、乳化剂用量等因素对特殊润湿性材料分离油水乳液的影响。实验结果表明,较低的温度对单层和双层筛网分离油包水(W/O)型和水包油(O/W)型乳液均有利;较低的过滤压力对W/O型乳液有利,过高的压力会直接影响筛网的疏水阻隔作用,双层筛网的分离机理决定了低过滤压力下分离无法进行,而更高的压力对双层筛网分离O/W型乳液更有利;低pH对两种类型的乳液分离均有利,随着pH的增大,分离效果下降;随着W/O型乳液含水率增大,单层筛网的分离效果不断下降,水在疏水筛网表面的占据会导致油的通过阻力迅速增大,甚至无法通过,而随着O/W型乳液含油率增大,双层筛网的分离效果呈增大趋势,这与水量下降导致的油水二次混合几率减少有关;乳化剂用量增加导致乳液稳定性增强,对两种类型乳液的分离均不利。
Influence factors of separation of emulsions by materials with special wettability
Self-developed stainless steel mesh screens with special wettability were used,and the effects of temperature,filtration pressure,pH,water-oil ratio,and emulsifier amount on the separation of oil-water emulsions by materials with special wettability were investigated.The results show that the lower temperature is favorable for the separation of water-in-oil(W/O)and oil-in-water(O/W)emulsions by single-layer and double-layer mesh screens,and the lower filtration pressure is favorable for the separation of W/O emulsions,but the higher pressure will directly affect the hydrophobicity of the mesh screens.In addition,the separation mechanism of the double-layer mesh screens determines that the separation is not possible under low filtration pressures.The higher pressure is more favorable for the separation of O/W emulsions by a double-layer mesh screen.Low pH is beneficial to the separation of both types of emulsions,and the separation effect decreases with the increase in pH;with the increase in water content of the W/O emulsions,the separation effect of single-layer mesh screen decreases,and the occupation of water on the surface of hydrophobic mesh screen leads to a rapid increase in the resistance of oil passing through the mesh screen or even makes the oil unable to pass through.With the rise of oil content in W/O emulsions,the separation effect of the double-layer mesh screen shows a rising trend,which is related to the decrease in the chances of secondary oil-water mixing caused by the decrease in the water content;the increase in emulsifier amount leads to stability enhancement of the emulsion and is detrimental to the separation of both types of emulsions.

oil-water separationspecial wettabilitymesh screenemulsioninfluence factors

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重庆工商大学 废油资源化技术与装备教育部工程研究中心,重庆 400067

油水分离 特殊润湿性 筛网 乳液 影响因素

2025

石油化工
中国石化集团资产经营管理有限公司 北京化工研究院 中国化工学会石油化工专业委员会

石油化工

北大核心
影响因子:0.916
ISSN:1000-8144
年,卷(期):2025.54(1)