实验科学与技术2025,Vol.23Issue(1) :74-81.DOI:10.12179/1672-4550.20230573

铈钒中空纳米柱阵列析氧催化剂的综合实验设计

Comprehensive Experiment Design on the Cerium-Vanadium Hollow Nanopillar Arrays Catalysts for Oxygen Evolution Reaction

吴飞超 秦艳 方静
实验科学与技术2025,Vol.23Issue(1) :74-81.DOI:10.12179/1672-4550.20230573

铈钒中空纳米柱阵列析氧催化剂的综合实验设计

Comprehensive Experiment Design on the Cerium-Vanadium Hollow Nanopillar Arrays Catalysts for Oxygen Evolution Reaction

吴飞超 1秦艳 1方静1
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作者信息

  • 1. 河北工业大学化工学院,天津 300130
  • 折叠

摘要

基于研究型教学的理念和教师的科研成果,设计了一个铈钒中空纳米柱阵列(CeV-HNA)用于电催化析氧反应(OER)的综合实验.该实验通过原位生长法在泡沫镍上制备钒基金属有机框架纳米柱阵列;然后通过铈盐蚀刻、高温焙烧构筑铈钒中空纳米柱阵列,得到自支撑式催化剂;再利用扫描电子显微镜、X射线衍射等测试手段考察所制备催化剂的形貌和组成;最后通过电化学测试研究催化剂的电催化析氧反应性能.该研究型实验兼具综合性、前沿性和趣味性,有助于锻炼学生的综合实践能力、激发学生的科研热情和培养学生的创新能力.

Abstract

A comprehensive experiment on the cerium-vanadium hollow nanopillar arrays(CeV-HNA)for electrocatalytic oxygen evolution reaction(OER)is designed based on the concept of research-oriented teaching and the scientific research achievements of the teacher.Vanadium based metal organic framework nanopillar arrays were firstly prepared on foam nickel by in-situ growth,and then Ce salt etching and high-temperature calcination were executed to construct CeV-HNA,achieving a freestanding catalyst.Furtherly,scanning electron microscopy,X-ray diffraction,X-ray photoelectron spectroscopy and other analytical testing methods were employed to characterize the structure of the prepared catalyst.Finally,its OER performance was investigated.This teaching experiment is comprehensive,cutting-edge and interesting,which contributes to exercise students'comprehensive practical abilities,stimulate their research enthusiasm and cultivate their innovation ability.

关键词

中空纳米柱阵列/电催化/析氧反应/研究型实验

Key words

hollow nanopillar arrays/electrocatalysis/oxygen evolution reaction/research-oriented experiment

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出版年

2025
实验科学与技术
四川省高教学会,电子科技大学

实验科学与技术

影响因子:0.762
ISSN:1672-4550
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