首页|二氧化硅包覆核壳结构催化剂的制备与应用研究进展

二氧化硅包覆核壳结构催化剂的制备与应用研究进展

RESEARCH PROGRESS ON PREPARATION AND APPLICATION OF SiO2 COATED CORE-SHELL CATALYSTS

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核壳材料作为一种复合型高效催化材料,由核心和壳层两部分有序组装而成,表现出优异的协同效应和新特性,在多相催化领域具有广阔的应用前景.其中,SiO2因无毒、化学惰性、光学透明、易于被修饰改性、价格低等优势而成为制备核壳结构催化剂的一种理想的壳层材料.介绍了溶胶-凝胶法、模板剂法、自组装法、表面沉积法等SiO2包覆的核壳结构催化剂的制备方法,并从择形催化、减少活性组分流失、防止纳米颗粒聚集和烧结三方面总结了 SiO2包覆的核壳结构催化剂在多相催化中的应用,并探讨了 SiO2包覆的核壳结构催化剂的未来发展趋势.
Core-shell materials,as a kind of composite catalyst,are composed of core and shell,which show excellent synergistic effect and new characteristics.SiO2 is an ideal shell material for developing core-shell catalysts because of its advantages such as non-toxicity,chemical inertness,optical transparency,simplicity of modification,and low cost.In this paper,the preparation methods of SiO2 coated core-shell catalysts,including the sol-gel approach,template method,self-assembly process,and surface deposition method were introduced in detail.Besides,the applications of SiO2 coated core-shell catalysts in heterogeneous catalysis,such as shape selective catalysis,reducing the loss of active components,preventing the aggregation of nanoparticles and sintering were discussed.The future development trend of core-shell catalysts coated with SiO2 was pointed out.

core-shell catalystSiO2 coatedpreparation methodsize selectivityactive componentsintering resistance

代巧玲、孙佳新、贾燕子、胡大为

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中石化石油化工科学研究院有限公司,北京 100083

核壳催化剂 SiO2包覆 制备方法 尺寸选择性 活性组分 抗烧结

中国石油化工股份有限公司合同项目

122100

2024

石油炼制与化工
中国石油化工股份有限公司石油化工科学研究院

石油炼制与化工

CSTPCD北大核心
影响因子:0.825
ISSN:1005-2399
年,卷(期):2024.55(3)
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