首页|农林废弃物制备生物炭对水中石油的吸附性能研究

农林废弃物制备生物炭对水中石油的吸附性能研究

STUDY ON ADSORPTION OF PETROLEUM IN WATER BY BIOCHAR PREPARED FROM AGRICULTURAL AND FORESTRY WASTES

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利用6种不同种类农林废弃物(包括小麦秸秆、花生壳、椰壳等)制备生物炭,研究不同生物炭对水中石油的吸附性能.系统考察生物炭种类及投加量、石油种类及浓度、吸附时间等因素对生物炭吸附水中石油效果的影响.结果表明,不同原料制备的生物炭对水中石油均具有较好的吸附性能,吸附量为142.70~493.86 mg/g.其中,以小麦秸秆制备的生物炭对石油的吸附量最大,其总孔体积明显大于其他生物炭,为0.155 cm3/g,含碳官能团也较多.小麦秸秆生物炭吸附水中石油时最佳投加量(p)为0.25 g/L,吸附平衡时间为60 min,吸附过程符合准二级动力学方程和Langmuir等温吸附模型,即更接近单分子层吸附.生物炭的吸油性能受到多种因素的影响,通过灰色关联度分析得出水中油浓度对生物炭的石油吸附量影响最大.
Six different types of agricultural and forestry wastes,such as wheat straw,peanut shell,coconut shell,etc.,were used to prepare biochar.The adsorption performance of different biochar on petroleum in water were studied.The effects of biochar type and dosage,oil type and concentration,adsorption time and other factors on the adsorption of oil in water by biochar were systematically investigated.The results showed that the biochar prepared from different raw materials had good adsorption capacity for oil in water,and the adsorption capacity was 142.70-493.86 mg/g.Among them,the biochar prepared from wheat straw with many carbon functional groups had the largest adsorption capacity for petroleum,and its total pore volume was 0.155 cm3/g,which was significantly larger than other biochars.The optimal dosage of wheat straw biochar for adsorption of petroleum in water was 0.25 g/L,and the adsorption equilibrium time was 60 min.The adsorption process conformed to the quasi-second-order kinetic equation and Langmuir isotherm adsorption model,that was,closer to the monolayer adsorption.The oil adsorption capacity of biochar was affected by many factors,and the oil concentration had the greatest impact on the adsorption capacity of biochar.

petroleumagricultural and forestry wastesbiochargrey correlation degreeinfluence factor

胡志强、徐昕玉、李向伟、石双欣、孙娟

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中石油江汉机械研究所有限公司,武汉 430000

中国石油大学(华东)化学化工学院

石油 农林废弃物 生物炭 灰色关联度 影响因素

中国石油科学研究与技术开发项目国家自然科学基金

2021DJ660641506117

2024

石油炼制与化工
中国石油化工股份有限公司石油化工科学研究院

石油炼制与化工

CSTPCD北大核心
影响因子:0.825
ISSN:1005-2399
年,卷(期):2024.55(4)
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