石油炼制与化工2024,Vol.55Issue(5) :14-19.

芳烃抽提蒸馏工艺(SED-BTX)的开发与应用

DEVELOPMENT AND APPLICATION OF AROMATICS EXTRACTION AND DISTILLATION PROCESS(SED-BTX)

赵明 蹇中立 田龙胜 唐文成
石油炼制与化工2024,Vol.55Issue(5) :14-19.

芳烃抽提蒸馏工艺(SED-BTX)的开发与应用

DEVELOPMENT AND APPLICATION OF AROMATICS EXTRACTION AND DISTILLATION PROCESS(SED-BTX)

赵明 1蹇中立 2田龙胜 1唐文成1
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作者信息

  • 1. 中石化石油化工科学研究院有限公司,北京 100083
  • 2. 中化泉州石化有限公司
  • 折叠

摘要

通过建立完善的相平衡数据包及过程模拟系统,开发了以加氢处理后的催化裂解加氢汽油为原料的芳烃抽提蒸馏(SED-BTX)新工艺.该工艺以抽提蒸馏为核心,将抽提蒸馏与液液抽提进行有机组合,利用各自的优势,既节能降碳,又实现轻质芳烃(BTX)产品高回收率、高纯度的目的.SED-BTX工艺在350 kt/a工业装置上应用一次开车成功,结果表明:苯产品收率达到99.9%,纯度(w)达到99.99%;甲苯产品收率达到99.9%,纯度达到99.98%;抽余油中非芳烃质量分数大于99.3%,环丁砜质量分数小于1 μg/g;包括精馏部分在内的全装置综合能耗为56.6 kgOE/t(1 kgOE=41.8 MJ),相比传统的液液抽提工艺降低25%.

Abstract

A new process for aromatics extraction and distillation(SED-BTX)of hydrogenated catalytic cracking gasoline was developed by establishing a comprehensive phase equilibrium data package and process simulation system.This process takes extraction distillation as the core,combines extraction distillation and liquid-liquid extraction organically,and makes use of their respective advantages to achieve the goals of energy conservation and carbon reduction,as well as high recovery rate and high purity of benzene-toluene-xylene(BTX)products.The SED-BTX process was successfully applied to a 350 kt/a industrial plant in one run.The results showed that the yield and purity of benzene product reached 99.9%and 99.99%respectively,that of toluene product reached 99.9%and 99.98%respectively,the non-aromatic content in the raffinate oil was over 99.3%,and the sulfolane content was less than 1 μg/g.The comprehensive energy consumption of the whole unit including the distillation unit was 56.6 kgOE/t(1 kgOE=41.8 MJ),which was 25%lower than the traditional liquid-liquid extraction process.

关键词

催化裂解汽油/芳烃/抽提蒸馏

Key words

catalytic cracking gasoline/aromatics/extraction and distillation

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基金项目

中国石化合同项目(223039)

出版年

2024
石油炼制与化工
中国石油化工股份有限公司石油化工科学研究院

石油炼制与化工

CSTPCD北大核心
影响因子:0.825
ISSN:1005-2399
参考文献量3
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