首页|4.0 Mt/a环烷基油加氢裂化装置多产重石脑油的实践

4.0 Mt/a环烷基油加氢裂化装置多产重石脑油的实践

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中海油惠州石化有限公司4.0 Mt/a加氢裂化装置采用RN-410C/RHC-210/RHC-220催化剂级配,通过分馏系统改造进行了多产优质化工原料的产品结构升级.标定结果表明,以焦化蜡油掺入量(w)为20.16%、氮质量分数为0.184 6%、密度(20 ℃)为0.910 g/cm3的混合蜡油为原料,在入口总压力为15.18 MPa、精制段和裂化段平均温度分别为385.6 ℃和389.3 ℃、采用一次通过流程的条件下,氢耗为2.98%,重石脑油收率为35.23%,尾油收率为10.69%.石脑油、喷气燃料、柴油产品指标均在合格范围内,其中喷气燃料烟点可达30 mm,柴油十六烷指数可达72.3、多环芳烃质量分数为1%,尾油BMCI为12;装置能耗为21.91 kgOE/t(1 kgOE=41.8 MJ),达到同类装置先进水平.重石脑油选择性从上周期的77.3%提高到了本周期的84.2%,表明催化剂级配及反应分区调控效果明显.
PRACTICE OF 4.0 Mt/a HYDROCRACKER FOR INCREASING HEAVY NAPHTHA PRODUCTION USING NAPHTHENE-BASE FEED
;The 4.0 Mt/a hydrocracker of CNOOC Huizhou Petrochemical Company Limited was modified by using RN-410C/RHC-210/RHC-220 graded catalysts and fractionation system revamping to upgrade the production of high-quality chemical feedstocks.The calibration results show that using the VGO feedstock,blended with 20.16%of CGO,with the nitrogen mass fraction of 0.184 6%and a density(20 ℃)of 0.910 g/cm3,under the conditions of an inlet pressure of 15.18 MPa,an average hydrotreating temperature of 385.6 ℃ and average hydrocracking temperature of 389.3 ℃,the hydrogen consumption is 2.98%,heavy naphtha yield is 35.23%,and tail oil yield is 10.69%.The naphtha,jet fuel,and diesel products can meet the specification requirements.The smoke point of jet fuel can reach 30 mm,the cetane index of diesel with 1%of polycyclic aromatics,can reach 72.3,and the BMCI value of tail oil is 12.The energy consumption of the unit is 21.91 kgEO/t(1 kgOE=41.8 MJ),reaching the advanced level of similar units.The selectivity of heavy naphtha increased from 77.3%in the previous cycle to 84.2%in this cycle,indicating a significant effect of catalyst gradation and reaction zone regulation.

naphthene-basehydrocrackingheavy naphthajet fueltail oil

周泽腾、郑港西、方友

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中海油惠州石化有限公司,广东惠州 516086

环烷基 加氢裂化 重石脑油 喷气燃料 尾油

2024

石油炼制与化工
中国石油化工股份有限公司石油化工科学研究院

石油炼制与化工

CSTPCD北大核心
影响因子:0.825
ISSN:1005-2399
年,卷(期):2024.55(5)
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