石油炼制与化工2024,Vol.55Issue(5) :38-44.

费-托合成油加氢裂化催化剂RCF-1的开发与工业应用

DEVELOPMENT AND COMMERCIAL APPLICATION OF HYDROCRACKING CATALYST RCF-1 FOR FISCHER-TROPSCH SYNTHETIC OIL

董松涛 李猛 王锦业 梁家林 胡志海 吴昊
石油炼制与化工2024,Vol.55Issue(5) :38-44.

费-托合成油加氢裂化催化剂RCF-1的开发与工业应用

DEVELOPMENT AND COMMERCIAL APPLICATION OF HYDROCRACKING CATALYST RCF-1 FOR FISCHER-TROPSCH SYNTHETIC OIL

董松涛 1李猛 1王锦业 1梁家林 1胡志海 1吴昊1
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作者信息

  • 1. 中石化石油化工科学研究院有限公司,北京 100083
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摘要

为加工费-托合成油,在优化酸性材料的类型、选择合适的介孔硅铝组分的基础上,开发了费-托合成油加氢裂化催化剂RCF-1,该催化剂具有温度敏感性低和中间馏分油选择性高等特点.工业应用结果表明,以RCF-1催化剂为基础,使用低温法费-托合成油加氢提质CFHL技术,异构加氢裂化单元生产的柴油馏分十六烷值为76,凝点为-33 ℃.稳定加氢和异构加氢裂化石脑油馏分适合作为蒸汽裂解料.

Abstract

In order to process Fischer-Tropsch(F-T)synthetic oil,on the basis of optimizing the acidic component of the catalyst to improve the temperature sensitivity of the catalyst and selecting the suitable mesoporous silica-aluminum components,catalyst RCF-1 for isomerization-hydrocracking of F-T wax was developed,which had low temperature sensitivity and high selectivity of middle-distillate.Based on this catalyst,the low-temperature F-T hydrotreating and hydrofinishing CFHL technology was employed.The commercial application of the catalyst RCF-1 showed that the cetane number and freezing point of the diesel distillate produced by the isomerization-hydrocracking unit were 76 and-33 ℃,respectively,using the low-temperature process for the hydrogenation of F-T synthetic CFHL.The stabilization-hydrogenation and isomerization-hydrocracking naphtha fractions are particularly suitable as steam cracking feed.

关键词

加氢裂化/费-托合成油/柴油/中间馏分油/催化剂

Key words

hydrocracking/Fischer-Tropsch synthetic oil/diesel/middle distillate/catalyst

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基金项目

国家重点研发计划(2021YFA1501204)

出版年

2024
石油炼制与化工
中国石油化工股份有限公司石油化工科学研究院

石油炼制与化工

CSTPCDCSCD北大核心
影响因子:0.825
ISSN:1005-2399
参考文献量1
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