首页|TiO2-Bi2WO6/Zn(CH3COO)2-ACF复合材料吸附-脱附耦合光催化降解烷烃能效探究

TiO2-Bi2WO6/Zn(CH3COO)2-ACF复合材料吸附-脱附耦合光催化降解烷烃能效探究

STUDY ON THE ENERGY EFFICIENCY OF PHOTOCATALYTIC DEGRADATION OF ALKANES BY COUPLING ADSORPTION-DESORPTION OF TiO2-Bi2WO6/Zn(CH3COO)2-ACF COMPOSITE

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采用水热和浸渍溶胶-凝胶法制备了 TiO2-Bi2WO6/Zn(CH3COO)2-ACF复合材料(记为TBZA),通过扫描电子显微镜、透射电子显微镜、X射线衍射、氮气吸附-脱附、紫外漫反射、光电流响应等手段表征其形貌和结构特性,并探究其在吸附-脱附耦合光催化反应器中对丙烷的降解性能.结果表明:制备的材料具有良好的光生电子-空穴分离率;在三级串联吸附-脱附耦合光催化反应器中,丙烷质量浓度为1 000 mg/m3,流量为1.2 m3/h,湿度为33%,温度为34 ℃,TBZA复合材料对丙烷吸附耦合光催化处理效率达到85.8%,相比于单一反应器提升了 48.9百分点;在紫外灯照射下,脱附温度为65 ℃时,TBZA复合材料的再生效果达到最佳,再生后对丙烷的总体转化率下降不足2%,表明TBZA材料作为催化剂具有良好的循环再生性能.
TiO2-Bi2WO6/Zn(CH3COO)2-ACF(TBZA)composite was prepared by hydrothermal and impregnation-sol-gel method,its morphology and structure of the composite were characterized by SEM,TEM,XRD,BET,UV-vis and I-T photocurrent response,and the degradation of propane in the adsorption-desorption coupling photocatalytic reactor was investigated.The results showed that the prepared materials had good photoelectron-hole separation rate.In the three-stage series adsorption-desorption coupled photocatalytic reactor,the propane mass concentration was 1 000 mg/m3,the flow rate was 1.2 m3/h,the humidity was 33%,and the temperature was 34 ℃.The photocatalytic efficiency of TBZA composite was 85.8%,which was 48.9 percentage points higher than that of a single reactor,and the overall propane conversion decreased by less than 2%when the desorption temperature was 65 ℃ under ultraviolet irradiation,indicating that TBZA material had good performance as catalyst for recycling.

propanecompositecoupled adsorption-desorptionphotocatalysistertiary reactor

王亚迪、杜斐然、毕玉玺、孙恩呈、纪国洋、刘芳、王永强

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中国石油大学(华东)化学化工学院,山东青岛 266580

中国石化胜利油田分公司技术检测中心

丙烷 复合材料 吸附-脱附耦合 光催化 三级反应器

中国石油安全与环保重点技术研究与推广项目国家科技重大专项子项目

2017D-46132016ZX05040-003

2024

石油炼制与化工
中国石油化工股份有限公司石油化工科学研究院

石油炼制与化工

CSTPCD北大核心
影响因子:0.825
ISSN:1005-2399
年,卷(期):2024.55(5)
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