石油炼制与化工2024,Vol.55Issue(5) :104-112.

TiO2-Bi2WO6/Zn(CH3COO)2-ACF复合材料吸附-脱附耦合光催化降解烷烃能效探究

STUDY ON THE ENERGY EFFICIENCY OF PHOTOCATALYTIC DEGRADATION OF ALKANES BY COUPLING ADSORPTION-DESORPTION OF TiO2-Bi2WO6/Zn(CH3COO)2-ACF COMPOSITE

王亚迪 杜斐然 毕玉玺 孙恩呈 纪国洋 刘芳 王永强
石油炼制与化工2024,Vol.55Issue(5) :104-112.

TiO2-Bi2WO6/Zn(CH3COO)2-ACF复合材料吸附-脱附耦合光催化降解烷烃能效探究

STUDY ON THE ENERGY EFFICIENCY OF PHOTOCATALYTIC DEGRADATION OF ALKANES BY COUPLING ADSORPTION-DESORPTION OF TiO2-Bi2WO6/Zn(CH3COO)2-ACF COMPOSITE

王亚迪 1杜斐然 1毕玉玺 1孙恩呈 2纪国洋 1刘芳 1王永强1
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作者信息

  • 1. 中国石油大学(华东)化学化工学院,山东青岛 266580
  • 2. 中国石油大学(华东)化学化工学院,山东青岛 266580;中国石化胜利油田分公司技术检测中心
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摘要

采用水热和浸渍溶胶-凝胶法制备了 TiO2-Bi2WO6/Zn(CH3COO)2-ACF复合材料(记为TBZA),通过扫描电子显微镜、透射电子显微镜、X射线衍射、氮气吸附-脱附、紫外漫反射、光电流响应等手段表征其形貌和结构特性,并探究其在吸附-脱附耦合光催化反应器中对丙烷的降解性能.结果表明:制备的材料具有良好的光生电子-空穴分离率;在三级串联吸附-脱附耦合光催化反应器中,丙烷质量浓度为1 000 mg/m3,流量为1.2 m3/h,湿度为33%,温度为34 ℃,TBZA复合材料对丙烷吸附耦合光催化处理效率达到85.8%,相比于单一反应器提升了 48.9百分点;在紫外灯照射下,脱附温度为65 ℃时,TBZA复合材料的再生效果达到最佳,再生后对丙烷的总体转化率下降不足2%,表明TBZA材料作为催化剂具有良好的循环再生性能.

Abstract

TiO2-Bi2WO6/Zn(CH3COO)2-ACF(TBZA)composite was prepared by hydrothermal and impregnation-sol-gel method,its morphology and structure of the composite were characterized by SEM,TEM,XRD,BET,UV-vis and I-T photocurrent response,and the degradation of propane in the adsorption-desorption coupling photocatalytic reactor was investigated.The results showed that the prepared materials had good photoelectron-hole separation rate.In the three-stage series adsorption-desorption coupled photocatalytic reactor,the propane mass concentration was 1 000 mg/m3,the flow rate was 1.2 m3/h,the humidity was 33%,and the temperature was 34 ℃.The photocatalytic efficiency of TBZA composite was 85.8%,which was 48.9 percentage points higher than that of a single reactor,and the overall propane conversion decreased by less than 2%when the desorption temperature was 65 ℃ under ultraviolet irradiation,indicating that TBZA material had good performance as catalyst for recycling.

关键词

丙烷/复合材料/吸附-脱附耦合/光催化/三级反应器

Key words

propane/composite/coupled adsorption-desorption/photocatalysis/tertiary reactor

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基金项目

中国石油安全与环保重点技术研究与推广项目(2017D-4613)

国家科技重大专项子项目(2016ZX05040-003)

出版年

2024
石油炼制与化工
中国石油化工股份有限公司石油化工科学研究院

石油炼制与化工

CSTPCD北大核心
影响因子:0.825
ISSN:1005-2399
参考文献量11
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