N-formylation of carbon dioxide(CO2)is the reaction of CO2 with organic amine in the presence of a reducing agent to form N-formamide compound.The N-formylation reaction of CO2 can be used as a resources to reduce greenhouse gas emissions,and can convert cheap CO2 into high value-added organic chemicals such as N,N-dimethylformamide and N-formylmorpholine,expands the CO2 downstream conversion and utilization of the reaction network.In this paper,the catalyst system,catalytic mechanism,and reaction process of N-formylation of CO2 in recent years were reviewed,and the problems in the research and future development of the reaction were also discussed.
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