CO2的N-甲酰化反应研究进展
PROGRESS IN N-FORMYLATION OF CARBON DIOXIDE
郭旭 1何鑫 1徐润 1夏国富1
作者信息
- 1. 中石化石油化工科学研究院有限公司,北京 100083
- 折叠
摘要
二氧化碳(CO2)的N-甲酰化反应是CO2在还原剂的作用下,与有机胺类化合物反应生成N-甲酰胺类化合物的反应.CO2的N-甲酰化反应既能够实现CO2的资源化利用,有助于减少温室气体排放,同时能够将廉价的CO2转化为高附加值的有机化学品,如N,N-二甲基甲酰胺和N-甲酰吗啉等,拓展CO2下游转化利用的反应网络.对近年来CO2的N-甲酰化反应的催化剂体系、催化机理和反应工艺等方面进行综述,阐述该反应研究过程中所面临的问题,并展望其未来发展方向.
Abstract
N-formylation of carbon dioxide(CO2)is the reaction of CO2 with organic amine in the presence of a reducing agent to form N-formamide compound.The N-formylation reaction of CO2 can be used as a resources to reduce greenhouse gas emissions,and can convert cheap CO2 into high value-added organic chemicals such as N,N-dimethylformamide and N-formylmorpholine,expands the CO2 downstream conversion and utilization of the reaction network.In this paper,the catalyst system,catalytic mechanism,and reaction process of N-formylation of CO2 in recent years were reviewed,and the problems in the research and future development of the reaction were also discussed.
关键词
CO2/N-甲酰化/催化剂/反应工艺Key words
CO2/N-formylation/catalyst/reaction technology引用本文复制引用
出版年
2024
NETL
NSTL
万方数据