石油炼制与化工2024,Vol.55Issue(8) :151-156.

基于生物滤池的炼化企业反渗透浓水处理研究

ADVANCED TREATMENT OF CONCENTRATED WASTEWATER FROM REVERSE OSMOSIS IN REFINERY AND PETROCHEMICAL ENTERPRISES BASED ON BIOLOGICAL FILTER

宋志敏 常成 高峰 桑军强 赵锐 孙钰林
石油炼制与化工2024,Vol.55Issue(8) :151-156.

基于生物滤池的炼化企业反渗透浓水处理研究

ADVANCED TREATMENT OF CONCENTRATED WASTEWATER FROM REVERSE OSMOSIS IN REFINERY AND PETROCHEMICAL ENTERPRISES BASED ON BIOLOGICAL FILTER

宋志敏 1常成 2高峰 2桑军强 2赵锐 2孙钰林2
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作者信息

  • 1. 中科(广东)炼化有限公司,广东湛江 524139
  • 2. 中石化石油化工科学研究院有限公司
  • 折叠

摘要

在炼化企业进行侧线试验考察反硝化生物滤池和碳基曝气生物滤池(CBAF)组合工艺对炼化企业污水回用过程中产生的反渗透浓水中总氮和有机物的去除效果,并分析处理过程中的有机物变化情况.结果表明:组合工艺可以有效去除反渗透浓水中的总氮(平均去除率为51.25%),降低化学需氧量(降低幅度为59.44%);反渗透浓水中主要污染物为腐殖酸类物质和溶解性微生物代谢产物,通过CBAF工艺处理后的污水中主要污染物的荧光强度显著降低;经过CBAF处理后,小分子酸类物质、构造块、小分子中性类物质、腐殖酸类物质和生物聚合物等亲水性有机碳的浓度分别可以降低81.65%,68.58%,63.85%,60.83%,49.30%;同时,由于载体的吸附作用,CBAF反应器对亲水性、疏水性有机碳都有较高的去除率(分别为64.20%和 74.58%).

Abstract

A side-line biological denitrification filter combined carbon-based biological aerated filter(CBAF)was used to investigate the removal efficiency of organic matter and total nitrogen in reverse osmosis(RO)concentrated wastewater produced in the process of refinery wastewater reuse,and the change of organic matter in the treatment process was analyzed.The results showed that the combined process could effectively remove the total nitrogen in the RO concentrated water(the average removal rate 51.25%)and reduce chemical oxygen demand(COD)by 59.44%.The main pollutants in the RO concentrated wastewater are humic acids and dissolved microbial metabolites,and the fluorescence intensity of the main pollutants in the wastewater was significantly decreased after the treatment with CBAF.The concentrations of hydrophilic organic carbons such as low molecular weight acids substances,building block,low molecular weight neutral substances,humic and biopolymer were reduced by 81.65%,68.58%,63.85%,60.83%and 49.3%,respectively.At the same time,due to the adsorption of the carrier,the CBAF reactor has a high removal rate of both hydrophilic and hydrophobic organic carbon(64.2%and 74.58%,respectively).

关键词

碳基曝气生物滤池/反渗透浓水/三维荧光/亲水性有机碳/腐殖酸类物质

Key words

carbon-based biological aerated filter/reverse osmosis concentrated water/excitation-emission-matrix spectra/hydrophilic organic carbons/humic acid substances

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出版年

2024
石油炼制与化工
中国石油化工股份有限公司石油化工科学研究院

石油炼制与化工

CSTPCD北大核心
影响因子:0.825
ISSN:1005-2399
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