首页|复配醇胺捕集CO2的微波解吸工艺研究

复配醇胺捕集CO2的微波解吸工艺研究

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针对传统醇胺法捕集CO2工艺需要高温(100 ℃以上)解吸的问题,从优化醇胺吸收液组成和优化解吸工艺两方面着手进行工艺优化,在优化CO2吸收条件的基础上提出了一种高效的微波加热解吸CO2方法,并优化了 CO2醇胺吸收液的微波加热解吸工艺.结果表明:复配醇胺优选由N-甲基二乙醇胺(MDEA)、哌嗪(PZ)、羟基乙二胺(AEEA)组成,当MDEA、PZ和AEEA的质量比为3∶1∶5时,复配醇胺的水溶液吸收CO2的效果最佳;以复配醇胺质量分数为20%的水溶液作为CO2吸收液,30 ℃下的CO2平衡吸收容量为1.15 mol/mol;利用微波加热,在95 ℃下解吸4 min时即可达到解吸平衡,CO2的解吸率达97.52%,基本实现全部解吸.与传统的加热解吸方法相比,相同温度下微波加热法的CO2解吸率提高62.25百分点,而且解吸时间显著缩短,实现了 CO2低温高效解吸.
MICROWAVE SWING REGENERATION OF CO2 IN BLENDED AMINE SOLUTION
In order to solve the problem of high temperature(above 100 ℃)desorption of CO2 captured by traditional process,based on the optimization of CO2 absorption conditions,a low-temperature and efficient microwave swing regeneration method was proposed.The results showed that when the mass ratio of the N-methyl ethanolamine(MDEA),piperazine(PZ)and 2-(2-aminoethylamino)ethanol(AEEA)was 3:1:5,the CO2 absorption efficiency of the mixed alcohol amine aqueous solution was the best.At an absorption temperature of 30 ℃,with the optimized blended alcohol amines as the absorption solution,when the mass fraction of the total amines was 20%,the CO2 absorption capacity of the alcohol amine aqueous solution reached 1.15 mol/mol;the desorption equilibrium could be reached at 95 ℃ for 4 min,the desorption rate of CO2 was 97.52%,and the desorption of CO2 was almost complete.Compared with the conventional heating desorption method,the CO2 desorption ratio of the microwave heating method at 95 ℃ increased by 62.25 percentage points,the desorption time was significantly shortened,and the high efficiency desorption of CO2 at low temperature was realized.

carbon dioxidecaptureblended alcohol aminesmicrowave heatingdesorption

明惠、张子珩、杨雪梅、杨凡、热则耶·热合米图力、杨田萌、侯军伟

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中国石油大学(北京)克拉玛依校区重质油国家重点实验室,新疆克拉玛依 834000

二氧化碳 捕集 复配醇胺 微波加热 解吸

新疆维吾尔自治区自然科学基金-地州科学基金项目新疆维吾尔自治区天山英才青年科技拔尖-基层科技骨干项目新疆维吾尔自治区天山英才青年科技拔尖-基层科技骨干项目国家自然科学基金项目

2022D01F602022TSYCJC00012023TSYCJC006552360003

2024

石油炼制与化工
中国石油化工股份有限公司石油化工科学研究院

石油炼制与化工

CSTPCD北大核心
影响因子:0.825
ISSN:1005-2399
年,卷(期):2024.55(10)