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制氢装置技术改造及低负荷运行分析

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某石化公司5×104 m3/h制氢装置在41%负荷时,出现加氢催化剂被还原和中变气空冷入口超温问题.对配氢系统和中变气换热系统进行技术改造,结果表明,25%负荷时转化入口总进料量高于41%负荷时转化入口总进料量,不仅避免了装置低负荷时转化炉管内介质偏流、加氢催化剂被还原和中变气空冷入口超温的问题,还利用中变气系统过剩的低温热产出235 t/h热水,回收热量创造经济效益达1 528万元/年,同时降低碳排放总量28 597 t/a.制氢装置操作弹性从50%~110%提高至25%~110%,更适用于全厂氢气系统平衡,避免氢气过剩.
Technical Transformation and Low Load Operation Analysis of Hydrogen Production Plant
The problems of hydrogenation catalyst reduction and air cooling inlet overtemperature at 41%load of 5×104 m3/h hydrogen production unit in a petrochemical company are introduced.Through the technical transformation of hydrogen distribution system and medium-gas heat exchange system,the results show that the total feed amount at the conversion inlet at 25%load is higher than that at 41%load.It not only avoids the medium bias in the reformer tube,the reduction of hydrogenation catalyst and the overtemperature of the medium-gas air cooling inlet at low load,but also uses the excess low-temperature heat of the medium-gas system to produce 235 t/h hot water.Annual recovery of heat to create economic benefits of 15.28 million yuan,while reducing the total carbon emissions of 28 597 t.The operating elasticity of hydrogen production unit is increased from 50%~110%to 25%~110%,which is more suitable for the balance of hydrogen system in the whole plant to avoid hydrogen excess.

hydrogen production technologytechnological transformationreformerlow loadrecovery

王国峰、国玲玲

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中国石油锦西石化公司,辽宁葫芦岛 125001

辽宁工程技术大学安全科学与工程学院,辽宁葫芦岛 125100

制氢 技术改造 转化炉 低负荷 回收

2024

石油石化绿色低碳
中国石油化工集团公司经济技术研究

石油石化绿色低碳

影响因子:0.23
ISSN:2095-0942
年,卷(期):2024.9(6)