首页|耐盐性PAM-AMPS/Fe3O4纳米减阻剂流变性

耐盐性PAM-AMPS/Fe3O4纳米减阻剂流变性

Rheological Properties of PAM-AMPS/Fe3O4 Nano Drag Reducing Agent With Salt Tolerance

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采用丙烯酰胺/2-丙烯酰胺基-2-甲基丙磺酸(AM/AMPS)共聚物接枝纳米Fe3O4合成了一种PAM-AMPS/Fe3O4纳米减阻剂,并利用动态流变仪研究了 PAM-AMPS/Fe3O4减阻剂的剪切稀释性,分析了纳米Fe3O4、盐含量及剪切作用对其流变行为的影响规律.结果表明:PAM-AMPS/Fe3O4纳米减阻剂的粒径为100~500 nm)黏均分子质量为4.99× 106 g/mol;在30 ℃下,剪切速率大于0.3 s-1时PAM-AMPS/Fe3O4减阻剂表现出显著的剪切稀释特征,该减阻剂具有更复杂的微观结构,其超临界质量分数为0.035%,相比空白聚合物表现出更优良的增黏性能和黏弹性;由于AMPS含有耐温耐盐基团,在NaCl和CaCl2质量分数分别为10%和5%的条件下,PAM-AMPS/Fe3O4减阻剂黏度保留率分别为69%和53%,表现出了较强的耐盐性;同时,该减阻剂在剪切速率1000 s-1条件下剪切3600、7200 s后的黏度回复率分别为100%和94%,表现出良好的耐剪切性.
In this study,a PAM-AMPS/Fe3 O4 nano drag reducing agent was synthesized by grafting acrylamide/2-acrylamido-2-methylpropane sulfonic acid(AM/AMPS)copolymer onto nano Fe3O4,the shear dilution of PAM-AMPS/Fe3O4 drag reducing agent was studied by dynamic rheometer,and the influence law of nano-Fe3O4,salt content and shearing action on their rheological behavior was also analyzed.The results show that the particle size of PAM-AMPS/Fe3O4 nano drag reducing agent is 100-500 nm,and the viscosity-average molecular weight is 4.99 X 106 g/mol.At 30 ℃,PAM-AMPS/Fe3 O4 drag reducing agent exhibits significant shear dilution characteristics when the shear rate is greater than 0.3 s-1.The drag reducing agent has a more complex microstructure,and its supercritical mass fraction is 0.035%.Compared with the blank polymer,it shows better viscosity enhancing ability and viscoelasticity behavior.As AMPS contains temperature and salt-tolerant groups,when the mass fraction of NaCl and CaCl2 is 10%and 5%,the viscosity retention rates of PAM-AMPS/Fe3O4 drag reducing agent can reach 69%and 53%respectively,showing a strong salt tolerance.Meanwhile,the viscosity recovery rates of the drag reducing agent after shearing for 3600 s and 7200 s at a shear rate of 1000 s-1 can reach 100%and 94%,respectively,demonstrating a good shear resistance.

drag reducing agentpolyacrylamidenano Fe3O4viscoelastic fluidsalt toleranceshear resistancerheological behavior

秦文龙、李璐、李国庆、李晗晰、秦国伟

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西安石油大学陕西省油气田特种增产技术重点实验室,陕西西安 710065

西安石油大学石油工程学院,陕西西安 710065

减阻剂 聚丙烯酰胺 纳米Fe3O4 黏弹性流体 耐盐性 耐剪切性 流变行为

国家自然科学基金项目西安石油大学研究生创新与实践能力培养计划项目

52174027YCS22213046

2024

石油学报(石油加工)
中国石油学会

石油学报(石油加工)

CSTPCD北大核心
影响因子:0.764
ISSN:1001-8719
年,卷(期):2024.40(1)
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