首页|封堵烟道气气窜用耐温冻胶实验研究

封堵烟道气气窜用耐温冻胶实验研究

Research on Temperature-Resistance Gel for Plugging Flue Gas Channeling

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针对烟道气存在的高温(110~130 ℃)油藏条件,使用低成本的部分水解聚丙烯酰胺(HPAM)与氨基树脂交联,制备了成胶时间、强度和热稳定性都适合作为封堵烟道气气窜的耐温聚合物冻胶.130 ℃通入3 MPa烟道气的条件下,通入烟道气的实验结果表明,聚合物冻胶受溶解的氧气影响造成热处理30 d内破胶,但冻胶强度表现出先增加、再稳定、后期失效的规律.复杂流变实验结果表明,热处理22 d后的冻胶在较高应变下不耐剪切,但冻胶弹性增加.大应变振幅扫描测试表明,冻胶在失效前的强度由于脱水收缩而增加,而这种特性有利于冻胶在有效期内的高效封堵.研究结果表明,构筑的聚合物冻胶适合作为封堵烟道气存在时、温度小于130 ℃的近井地带段塞使用.
In response to the high temperature(110-130 ℃)reservoir of flue gas,a temperature-resistant polymer gel was performed by low-cost HPAM crosslinked by amino resin,which is applicable for plugging flue gas channeling due to its suitable gelation time,gel strength and thermal stability.The experimental results show that the polymer gel was damaged by dissolved oxygen within 30 days of heat treatment in the presence of flue gas under the condition of 3 MPa and 130 ℃,and the gel strength initially increased,then maintained stable,and was damaged at last.The complex rheological method showed that the gel has a characteristic of shear intolerance under large strain,but the gel elasticity is increased after heat treatment for 22 days.The large amplitude oscillatory shear tests show that the strength of the gel is increased before being damaged due to its shrinkage and dehydration,which is conducive to efficient plugging during the effective period of gel.The research results indicate that the polymer gel can be used as a slug in the near-wellbore area where the flue gas exists and the temperature is less than 130 ℃.

carbon capture,untilization and storage(CCUS)fluegaspolymer gelviscoelasticitygel stability

刘明嘉、葛际江、陈伟雄、马爱青

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中国石油大学(华东)石油工程学院,山东青岛 266580

中石化胜利油田分公司石油工程技术研究院,山东东营 257000

碳捕集、利用与封存(CCUS) 烟道气 聚合物冻胶 黏弹性 冻胶稳定性

中国石油重大科技项目

ZD2019-183-007

2024

石油学报(石油加工)
中国石油学会

石油学报(石油加工)

CSTPCD北大核心
影响因子:0.764
ISSN:1001-8719
年,卷(期):2024.40(4)
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