石油管材与仪器2024,Vol.10Issue(3) :95-100.DOI:10.19459/j.cnki.61-1500/te.2024.03.016

地面集输玻璃钢管结蜡原因与机理分析研究

Analysis on the Causes and Mechanisms of Wax Formation in Ground Gathering and Transportation Fiberglass Pipes

李磊 贾福生 孙坤 张欣欣 齐国权 李厚补 朱文峰
石油管材与仪器2024,Vol.10Issue(3) :95-100.DOI:10.19459/j.cnki.61-1500/te.2024.03.016

地面集输玻璃钢管结蜡原因与机理分析研究

Analysis on the Causes and Mechanisms of Wax Formation in Ground Gathering and Transportation Fiberglass Pipes

李磊 1贾福生 2孙坤 3张欣欣 2齐国权 1李厚补 1朱文峰1
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作者信息

  • 1. 中国石油集团工程材料研究院有限公司,油气钻采输送装备全国重点实验室 陕西 西安 710077
  • 2. 塔里木油田公司哈得采油气管理区 新疆 库尔勒 841000
  • 3. 吐哈油田公司吐鲁番采油管理区 新疆 哈密 839000
  • 折叠

摘要

某油田地面集输玻璃钢管线投产后出现蜡堵,严重影响油田正常生产.为了确定玻璃钢管结蜡原因与机理,从具有不同结蜡程度的3 条在役玻璃钢管线截取试样,开展宏观检查、理化试验和润湿性分析等对比试验研究.结果表明,该3 条玻璃钢管试样的成分结构、树脂含量、硬度和固化程度未见明显差异,符合玻璃钢管的标准要求,它们对柴油均表现为超亲油状态,润湿性未见明显差异.结蜡程度的不同主要是由管道运行温度所致,低流速、低气液比加速蜡沉积.玻璃钢管结蜡机理与钢质管道基本一致,为分子扩散机理,但玻璃钢管的临界表面张力、导热系数和粗糙度更低,使其不易发生蜡晶的沉积与聚集,展现出更佳的防结蜡性能.通过降低管材表面张力和实现疏油状态,将是提升玻璃钢管防结蜡性能的有效途径.

Abstract

After the production of a fiberglass pipeline for surface gathering and transportation in a certain oilfield,wax blockage occurred,seriously affecting the normal production of the oilfield.To clarify the causes and mechanisms of wax formation in fiberglass pipes,samples were taken from three in-service fiberglass pipelines with different degrees of wax formation,and comparative experimental studies were con-ducted,including macroscopic inspection,physical and chemical tests,and wettability analysis.The results showed that there were no sig-nificant differences in the composition structure,resin content,hardness,and curing degree of the three glass fiber reinforced plastic speci-mens,which met the standard requirements of glass fiber reinforced plasticpipe.They all showed a super lipophilic state towards diesel and no significant difference in wettability.The difference in wax deposition degree was mainly caused by the operating temperature of the pipe-line,and low flow rate and low gas-liquid ratio accelerated wax deposition.The waxing mechanism of fiberglass pipes is basically the same as that of steel pipes,which is a molecular diffusion mechanism.However,the critical surface tension,thermal conductivity,and roughness of fiberglass pipes are lower,making them less prone to wax crystal deposition and aggregation,demonstrating better anti-waxing perform-ance.Reducing the surface tension of the pipe and achieving an oil repellent state will be an effective way to improve the anti-waxing per-formance of fiberglass pipes.

关键词

集输管线/含蜡原油/玻璃钢管/结蜡原因/结蜡机理

Key words

gathering and transmission pipeline/wax containing crude oil/fiberglass reinforced plastic pipe/reason for wax formation/wax formation mechanism

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基金项目

国家自然科学基金面上项目(52274069)

陕西省自然科学基础研究计划(2023-JC-QN-0433)

中国石油天然气集团有限公司基础研究和战略储备技术研究基金(2023DQ03-05)

出版年

2024
石油管材与仪器
中国石油集团 东方地球物理勘探有限责任公司

石油管材与仪器

影响因子:0.129
ISSN:1004-9134
参考文献量7
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