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矿物掺合料对混凝土抗碳化性能影响的灰色关联分析

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通过改变矿渣、粉煤灰的掺量和组合方式以及水胶比,分析了矿物掺合料对混凝土抗碳化性能的影响.同时,基于灰色关联理论对混凝土抗碳化性能受各因素的影响程度进行了定量分析,并结合硬化浆体水化产物的化学组成分析探讨了矿物掺合料的影响机理.研究结果表明:掺入矿物掺合料和增大水胶比均会使混凝土碳化深度增大,当单掺Ⅰ级粉煤灰掺量超过40%后,混凝土碳化深度增长速度极快;在总掺量一致的前提下,复掺矿物掺合料组的混凝土抗碳化性能要优于单掺粉煤灰组的混凝土;矿渣和粉煤灰的不同组合方式中,S105矿渣+Ⅰ级粉煤灰组的混凝土碳化深度最大;各影响因素对混凝土抗碳化性能的影响程度从高到低排序为水胶比>单掺Ⅰ级粉煤灰掺量>复掺S95矿渣+Ⅰ级粉煤灰总量>矿物掺合料组合方式;XRD分析表明,随着粉煤灰掺量的增加,Ca(OH)2的衍射峰高度逐渐降低,说明粉煤灰的火山灰反应消耗了大量的Ca(OH)2,从而逐步降低了混凝土的抗碳化性能.
Grey Correlation Analysis of Influence of Mineral Admixtures on Concrete Carbonation Resistance
The influence of mineral admixtures on concrete carbonation resistance was analyzed by changing the dosage and combination ways of slag and fly ash,as well as the water-binder ratio.At the same time,a quantitative analysis was conducted on the influence degree of various factors on concrete carbonation resistance by grey correlation theory.The inflence mechanism of mineral admixtures was explored by the chemical composition of the hydration products of the hardened slurry.The research results show that both the addition of mineral admixtures and increasing the water-binder ratio can increase concrete carbonation depth.When the single addition of Grade Ⅰ fly ash exceeds 40%,the carbonation depth increases rapidly;Under the same total dosage,the concrete carbonation resistance with com-pound mineral admixture group is better than that of single fly ash group;Among the different combinations of slag and fly ash,the concrete carbonation depth of the S105 slag+Grade Ⅰ fly ash group is the highest;The impact degree of various factors is ranked from high to low as follows:water-binder ratio>single addition of Grade Ⅰ fly ash content>composite addition total amount of S95 slag+Grade Ⅰ fly ash>combination of mineral admixtures;XRD analysis shows that the diffraction peak height of Ca(OH)2 gradually decreases with the increase of fly ash content,indicating that the volcanic ash reaction of fly ash consumes a large amount of Ca(OH)2,thereby gradually reduced concrete carbonation resistance.

concretemineral admixturescarbonation resistancegrey correlationinfluence degree

闫博华、潘慧敏

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山西省交通规划勘察设计院有限公司,山西太原 030032

燕山大学建筑工程与力学学院,河北秦皇岛 066004

混凝土 矿物掺合料 抗碳化性能 灰色关联 影响程度

国家自然科学基金

51608469

2024

市政技术
中国市政工程协会 北京市政路桥股份有限公司 北京市政建设集团有限责任公司 北京市市政工程研究院

市政技术

影响因子:0.385
ISSN:1009-7767
年,卷(期):2024.42(2)
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