首页|层状双金属氢氧化物(LDHs)对SBS改性沥青抗老化性能的影响研究

层状双金属氢氧化物(LDHs)对SBS改性沥青抗老化性能的影响研究

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为了增强SBS改性沥青(SMB)的抗老化性能,利用层状双金属氢氧化物(LDHs)的独特结构对SMB进行改性.研究了LDHs对SMB的物理性能、高低温流变性能和化学结构的影响规律.研究结果表明:LDHs的加入有助于提高SMB的弹性性能,提升SMB的高温稳定性能;老化后,沥青分子发生氧化反应导致SMB中含氧官能团(S=O和C=O)含量增加,同时SBS分子链发生断裂引起SMB中碳碳双键官能团(C=C)含量减少,这些变化使SMB的物理性能、高温抗车辙性能和低温抗疲劳开裂性能发生劣化,导致其变硬变脆;LDHs的加入可以阻止沥青分子的氧化反应和SBS分子链断裂,减缓沥青分子的老化和SBS老化降解,减轻老化对SMB物理性能和高低温流变性能的破坏,增强SMB的抗老化能力,为建设长寿命的SMB路面提供技术支持.
Effect of Layered Double Hydroxides(LDHs)on Anti-aging Properties of SBS Modified Asphalt
In order to enhance the anti-aging performance of styrene-butadiene-styrene(SBS)modified bitumen(SMB),SMB was modified by the special structure of layered double hydroxides(LDHs)in this study.The effect of LDHs on the physical properties,high or low temperature rheological properties and chemical structure of SMB was studied.The result showes that the addition of LDHs can improve the elastic properties of SMB and enhance its high-temperature stability;After aging,oxidation reactions of bitumen molecules caused the increase of oxygen-containing functional groups(S=O and C=O)content in SMB.At the same time,the SBS molecular chains broke down,which resulted in the decrease of carbon-carbon double bonds(C=C)content in SMB.All the changes made the physical properties,high-temperature rutting resistance,and low-temperature fatigue cracking resistance of SMB deteriorated.And SMB became hard and brittle;The addition of LDHs can prevent the oxidation reaction of bitumen molecules and the breaking of SBS molecular chains to retard the aging of bitumen molecules and SBS degradation,mitigate the damage to the physical properties and high or low temperature rheological properties of SMB,and enhance the anti-aging capacity of SMB,which provide technical support for the long-life SMB pavement.

SBS modified bitumen(SMB)layered double hydroxides(LDHs)physical propertiesrheological propertieschemical structureanti-aging capacity

汪婷、谈振华、章灿林

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福州大学福建省高校测试中心,福建福州 350108

福州大学土木工程学院,福建福州 350108

SBS改性沥青(SMB) 层状双金属氢氧化物(LDHs) 物理性能 流变性能 化学结构 抗老化能力

2024

市政技术
中国市政工程协会 北京市政路桥股份有限公司 北京市政建设集团有限责任公司 北京市市政工程研究院

市政技术

影响因子:0.385
ISSN:1009-7767
年,卷(期):2024.42(10)