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玄武岩纤维表面改性及其对砂浆性能的影响

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为了提高玄武岩纤维与水泥基材料界面的结合力,采用不同质量分数硅烷偶联剂(KH550)溶液、纳米SiO2和KH550复合液对玄武岩纤维进行表面改性,从改性玄武岩纤维的表面形貌、纤维接枝率、纤维耐腐蚀性能和掺改性纤维后水泥砂浆的力学性能等方面进行分析.结果表明:不论是采用KH550溶液、还是采用纳米SiO2和KH550复合液对玄武岩纤维表面改性后,玄武岩纤维表面均会附着颗粒物,且随着KH550质量分数增加和纳米SiO2掺量增加,附着的颗粒物、纤维的接枝率均逐渐增加,耐腐蚀性能逐渐提升;掺改性玄武岩纤维后水泥砂浆的抗压强度和抗折强度均有所提高,这是因为玄武岩纤维表面改性增大了玄武岩纤维与水泥基材料的机械咬合力和化学键合力.
Surface Modification of Basalt Fiber and Its Influence on Mortar Properties
In order to improve the interface bonding force between basalt fiber and cement-based material,different mass fractions of silane coupling agent(KH550)solution,nano SiO2 and KH550 composite solution were used to modify the surface of basalt fibers.The surface morphology,fiber grafting rate,fiber corrosion resistance and mechanical properties of modified fiber cement mortar were studied.The results show that,whether using KH550 solution or nano SiO2 and KH550 composite solution to modify the surface of basalt fibers,all basalt fibers have particles attached to their surfaces.As the mass fraction of KH550 increases and the content of nano SiO2 increases,the attached particles and grafting rate of fibers gradually increases,and the corrosion resistance gradually improves.After adding modified basalt fibers,the compressive strength and flexural strength of cement mortar have been improved.This is because the surface modification of basalt fibers increases the mechanical biting force and chemical bonding force between basalt fibers and cement-based materials.

surface modification of basalt fiberKH550nano SiO2experimental studymortar mechanical propertiesgrafting rate

李林香、谭盐宾、齐婧、杨鲁、葛昕、吴俊杰、王志勇

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中国铁道科学研究院集团有限公司 铁道建筑研究所, 北京 100081

中国铁道科学研究院集团有限公司 高速铁路轨道系统全国重点实验室, 北京 100081

玄武岩纤维表面改性 KH550 纳米SiO2 试验研究 砂浆力学性能 接枝率

浙江省科技计划中国铁道科学研究院集团有限公司基金

2021C010292022YJ331

2024

铁道建筑
中国铁道科学研究院

铁道建筑

北大核心
影响因子:0.623
ISSN:1003-1995
年,卷(期):2024.64(1)
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