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新型粘结抑尘剂的制备及性能研究

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为解决煤尘污染给环境和工人带来的危害,文中利用瓜尔胶(guar gum,GG)、聚乙烯醇(polyvinyl alcohol,PVA)和丙烯酸(acrylic acid,AA)分子间的氢键相互作用,制备了一种环境友好的新型水凝胶抑尘剂瓜尔胶-聚乙烯醇-丙烯酸(GG-PVA-AA),旨在改善目前水凝胶抑尘剂较差的力学性能与粘结性能。扫描电镜下显示,喷涂该抑尘剂后,GG-PVA-AA能在煤尘颗粒之间形成一层致密的固化膜,将煤粉颗粒粘结在一起。该致密防护结构能有效抑制煤尘的产生和扩散,达到理想的抑尘效果;抗风蚀实验结果表明用GG-PVA-AA粉尘抑制剂处理的煤粉在强风9 m/s侵蚀条件下质量损失为15。9%,可见GG-PVA-AA粉尘抑制剂具有良好的抗风蚀性;此外,分析了抑尘剂/煤体系和水/煤体系的相互吸附过程,可知抑尘剂分子在煤表面的吸附程度比水分子更大,从微观角度揭示了其抑尘机理。
Study on preparation and properties of a new adhesive dust suppressant
In order to solve the harm of coal dust pollution to the environment and workers,a new environmentally friendly hydrogel dust suppressant GG-PVA-AA(guar gum-polyvinyl alcohol-acrylic acid)was prepared by using the hydrogen bond interaction between GG(guar gum),PVA(polyvinyl alcohol)and AA(acrylic acid),aiming at improving the poor mechanical properties and adhesive properties of the current hydrogel dust suppressant.Scanning electron microscope shows that GG-PVA-AA can form a dense solidified film between coal dust particles after spraying the dust suppressant,and bind the coal dust particles together.The dense protective structure can effectively inhibit the generation and diffusion of coal dust and achieve ideal dust suppression effect.The experimental results of the wind erosion resistance show that the mass loss of pulverized coal treated with GG-PVA-AA dust inhibitor is 15.9%under the condition of strong wind erosion of 9 m/s,which shows that GG-PVA-AA dust inhibitor has good wind erosion resistance.Moreover,the mutual adsorption process of the dust suppressant/coal system and the water/coal system were analyzed,revealing that the adsorption of dust suppressant molecules is larger than that of water molecules,thus uncorering the dust suppressant mechanism from a micrscopic perspective.

coal dust pollutionhydrogel dust suppressantadhesive propertywind erosion resistancedust suppression mechanism

张云祥、奚志林

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天津理工大学环境科学与安全工程学院,天津 300384

煤尘污染 水凝胶抑尘剂 粘结性能 抗风蚀性 抑尘机理

2025

天津理工大学学报
天津理工大学

天津理工大学学报

影响因子:0.307
ISSN:1673-095X
年,卷(期):2025.41(2)