首页|重铬酸钾容量法和高频红外碳硫仪法测定土壤中有机质含量的比较研究

重铬酸钾容量法和高频红外碳硫仪法测定土壤中有机质含量的比较研究

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土壤有机质含量是土壤肥力的重要指标,准确测定其含量对农业生产和土壤环境监测具有现实意义。目前关于土壤有机质含量测定的方法主要有两种:一类是重铬酸钾容量法;另一类是使用高频红外碳硫仪进行测定,两种方法都是通过测定土壤中有机碳的含量,再乘以校正系数间接求得有机质的含量。选用6种含量不同的土壤和沉积物标准物质,通过两种方法分别进行测定,考察了两种方法测定数据的准确性和精密度,当样品有机质含量较低时,两种方法的精密度都较差,但重铬酸钾容量法测定结果更加稳定、准确,随着有机质含量的增加,两种方法的测定结果均表现出稳定的状态,相比较而言,高频红外碳硫仪法前处理简单,测定方便,适用于大批量土壤样品有机质的快速测定。选取豫北某地区土壤样品进行验证实验,使用重铬酸钾容量法和高频红外碳硫仪法测定的有机质含量在15。8~29。0 g/kg,两种方法测定结果基本一致,相对偏差分别为0。8~1。1和0。6~1。0g/kg,精密度2。8%~6。1%和2。1%~6。2%,符合相关标准的检测要求。
Comparative study on the determination of organic matter content in soil using potassium dichromate volumetric method and high-frequency infrared carbon sulfur analyzer method
The content of soil organic matter is an important indicator of soil fertility,and accurate measurement of its content has practical significance for agricultural production and soil environmental monitoring.There are currently two main methods for determining soil organic matter content:one is the potassium dichromate volumetric method,the other is the use of high-frequency infrared carbon and sulfur analyzer for measurement.Both methods indirectly determine the content of organic matter in soil by measuring the content of organic carbon and multiplying it by a correction coefficient.This article selected six soil and sediment reference materials with different contents and conducted measurements using two methods to examine the accuracy and precision of these methods.When the organic matter content of the sample was low,the precision of both methods was poor,but the potassium dichromate volumetric method was more stable and accurate.As the organic matter content increased,the results of both methods showed a stable state.In comparison,the high-frequency infrared carbon sulfur analyzer method had simple pre-treatment and convenient determination,and was suitable for rapid determination of organic matter in large quantities of soil samples.Selecting soil samples from a certain area in northern Henan for validation experiments,the organic matter content was determined using potassium dichromate volumetric method and high-frequency infrared carbon sulfur analyzer method,ranging from 15.8 to 29.0 g/kg.The results obtained by the two methods were basically consistent,with relative deviations of 0.8-1.1 g/kg and 0.6-1.0 g/kg,and precision of 2.8%-6.1%and 2.1%-6.2%,which met the detection requirements of relevant standards.

soil organic mattercapacity methodhigh frequency infrared carbon and sulfur analyzercontrastive study

蔡兴、王腾飞、付小波、闫晓、张金燕、王凯凯、刘宗超、文田耀、孙文军

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河南省第一地质矿产调查院有限公司,河南 洛阳 471000

河南省生态环境与勘查地球化学应用工程技术研究中心,河南 洛阳 471000

土壤有机质 容量法 高频红外碳硫仪 对比研究

2024

中国土壤与肥料
中国农业科学院农业资源与农业区划研究所 中国植物营养与肥料学会

中国土壤与肥料

CSTPCD北大核心
影响因子:1.197
ISSN:1673-6257
年,卷(期):2024.(7)