首页|石灰回转窑真实烟气条件下有机胺法CO2捕集试验

石灰回转窑真实烟气条件下有机胺法CO2捕集试验

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为推动有机胺法CO2捕集工艺在钢铁行业的应用,在石灰石回转窑炉真实烟气条件下开展了有机胺法CO2捕集侧线试验,考察了有机胺溶液质量分数、烟气流量、溶液喷淋量、吸收温度、油浴温度和再生压力等关键参数对捕集系统CO2捕集性能的影响。结果表明,在最优试验条件(有机胺溶液质量分数为25。0%、烟气流量为20 m3/h、溶液喷淋量为70 L/h、吸收温度为30℃、油浴温度为115℃以及再生压力为10 kPa)下,捕集系统CO2捕集率和解吸酸气量分别为94%和1。22 m3/h。在最优试验条件下进行的480 h连续试验结果显示,捕集系统CO2捕集率平均值为94%,解吸酸气量平均值为1。22 m3/h,CO2捕集系统表现出良好的稳定性,证明有机胺法应用于石灰回转窑烟气CO2捕集技术可行。
Experiment of CO2 capture by organic amine method under lime rotary kiln real flue gas condition
To promote the application of the organic amine CO2 capture process in the steel industry,the sideline test of CO2 capture by organic amine method was carried out under lime rotary kiln real flue gas condition.The effects of key parameters such as the mass fraction of organic amine solution,flue gas flow,solution spray amount,absorption temperature,oil bath temperature and regeneration pressure on CO2 capture performance of the capture system were investigated.The results show that under the optimal test conditions(the mass fraction of organic amine solution of 25.0%,the flue gas flow of 20 m3/h,the solution spray amount of 70 L/h,the absorption temperature of 30℃,the oil bath temperature of 115℃and the regeneration pressure of 10 kPa),the CO2 capture efficiency and the amount of desorption acid gas of the capture system are 94%and 1.22 m3/h,respectively.The results of 480 h continuous test under the optimal test conditions show that the average value of CO2 capture efficiency of the capture system is 94%,and the average value of desorption acid gas amount of the capture system is 1.22 m3/h.The CO2 capture system shows good stability,which proves that the application of organic amine method to the lime rotary kiln flue gas CO2 capture technology is feasible.

lime rotary kilnflue gasCO2 captureorganic amine absorption method

邱正秋、皇甫林、杨强、段晓东、鄢攀邻

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攀钢集团研究院有限公司 钒钛资源综合利用国家重点实验室,四川 攀枝花 617000

成都先进金属材料产业技术研究院股份有限公司,四川 成都 610305

攀钢集团冶金材料有限责任公司,四川 攀枝花 617023

石灰回转窑 烟气 CO2捕集 有机胺吸收法

2024

天然气化工—C1化学与化工
西南化工研究设计院有限公司 全国天然气化工与碳一化工信息中心

天然气化工—C1化学与化工

CSTPCD北大核心
影响因子:0.814
ISSN:1001-9219
年,卷(期):2024.49(7)