首页|过渡金属硫化物催化剂性能优化与光催化水分解制氢研究进展

过渡金属硫化物催化剂性能优化与光催化水分解制氢研究进展

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过渡金属硫化物催化剂展现出较高的光催化水分解制氢性能,且储量丰富、价格低廉,是替代贵金属铂催化剂的理想选择。综述了过渡金属硫化物催化剂的制备方法、结构形貌和产氢速率,讨论了提升过渡金属硫化物催化剂及其复合催化剂的光催化水分解制氢催化效率的策略:扩展光吸收范围、增强光生电子-空穴对分离和促进催化剂表面反应,以制备更为高效的、达到商业要求的过渡金属硫化物催化剂。最后,对未来有关过渡金属硫化物催化剂的光催化水分解制氢领域的研究进行了展望。
Research progress in optimization of transition metal sulfide catalysts and hydrogen production from photocatalytic water splitting
Transition metal sulfide catalysts with abundant reserves and low prices exhibit high activity for hydrogen production from photocatalytic water splitting and are ideal choices to replace precious metal platinum catalysts.The preparation methods,structural morphologies and hydrogen production rates of transition metal sulfide catalysts for hydrogen production from photocatalytic water splitting were reviewed.Strategies for improving the efficiency of hydrogen production from photocatalytic water splitting by transition metal sulfide catalysts and their composite catalysts were discussed,including expanding the light absorption range,enhancing the separation of photogenerated electron-hole pairs and promoting catalyst surface reactions,to prepare more efficient transition metal sulfide catalysts that meet commercial requirements.At last,the future research trends in the field of hydrogen production from photocatalytic water splitting by transition metal sulfide catalysts were prospected.

hydrogentransition metal sulfidesphotocatalysiswater splittingsolar energy

王庭伟、端木传嵩、孟新宇、邹家富、潘云翔

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淮阴工学院化学工程学院,江苏淮安 223003

上海交通大学化学化工学院,上海 200240

氢气 过渡金属硫化物 光催化 水分解 太阳能

国家自然科学基金

21922807

2024

天然气化工—C1化学与化工
西南化工研究设计院有限公司 全国天然气化工与碳一化工信息中心

天然气化工—C1化学与化工

CSTPCD北大核心
影响因子:0.814
ISSN:1001-9219
年,卷(期):2024.49(9)