首页|Ru-FeOOH@NiFe LDH纳米片制备及其电解水析氢性能研究

Ru-FeOOH@NiFe LDH纳米片制备及其电解水析氢性能研究

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电解水制氢技术的开发对于促进低碳发展具有重要意义,设计高效稳定的催化剂至关重要。通过一步水热法在泡沫镍基底上合成了Ru-FeOOH@NiFe LDH催化剂,用于电催化水分解制氢。通过SEM、TEM、XRD和XPS对催化剂进行了表征分析。结果表明,钌的引入可以调节催化剂的电子结构,增强金属-载体相互作用,使得Ru-FeOOH@NiFe LDH表现出良好的电催化性能。当电流密度为10 mA/cm2时,Ru-FeOOH@NiFe LDH所需过电位为95 mV,Tafel斜率为80。6 mV/dec,其电催化性能明显优于FeOOH@NiFe LDH。在相同反应条件下,Ru-FeOOH@NiFe LDH可稳定运行15 h。
Study on preparation and properties of Ru-FeOOH@NiFe LDH nanosheets for electrocatalytic hydrogen evolution
The development of hydrogen production technology by electrolytic water is important to promote the low-carbon development,among which the design of efficient and stable catalysts is essential.Ru-FeOOH@NiFe LDH catalyst was synthesized on nickel foam substrate by one-step hydrothermal method and characterized by SEM,TEM,XRD and XPS.The results show that the introduction of Ru can adjust the electronic structure of the catalyst,improve the interaction between metal and supports,and the catalyst shows better electrocatalytic performance.The required overpotential of Ru-FeOOH@NiFe LDH is 95 mV at the current density of 10 mA/cm2 with a low Tafel slope of 80.6 mV/dec,which indicates that the electrocatalytic performance of Ru-FeOOH@NiFe LDH is better than that of FeOOH@NiFe LDH.Ru-FeOOH@NiFe LDH can catalyze the reaction stably for 15 h under the same reaction conditions.

water electrolysishydrogen evolution reactionelectrocatalystNiFe layered double hydroxide

杨苗、李攀、杨红、邵圣娟、王峰、牛宇岚

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太原工业学院 化学与化工系,山西 太原 030008

太原工业学院 环境与安全工程系,山西 太原 030008

电解水 析氢反应 电催化剂 NiFe层状双金属氢氧化物

2024

天然气化工—C1化学与化工
西南化工研究设计院有限公司 全国天然气化工与碳一化工信息中心

天然气化工—C1化学与化工

CSTPCD北大核心
影响因子:0.814
ISSN:1001-9219
年,卷(期):2024.49(12)