首页|呋虫胺在土壤中的降解及移动性研究

呋虫胺在土壤中的降解及移动性研究

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呋虫胺的大量使用会引起土壤和地下水污染、生态环境恶化等问题,研究呋虫胺在土壤中的降解特性和移动性,对呋虫胺环境安全性评价具有重要意义。采用室内模拟试验,研究了呋虫胺在3种不同类型土壤中的降解和移动性以及土壤中不同因子对呋虫胺降解的影响。结果表明,呋虫胺在不同类型土壤降解的顺序依次为:南京黄棕壤>东北黑土>江西红壤,半衰期分别为35.2、92.4、154.0 d。呋虫胺在南京黄棕壤中属于中等降解,在江西红壤和东北黑土中均属于较难降解。土壤湿度越大,呋虫胺降解越快,当土壤湿度为饱和含水量80%时,会对微生物生长产生抑制作用,降解速率减慢。微生物和有机质在土壤降解过程中起着重要的作用,微生物和有机质存在的条件下呋虫胺土壤降解分别加快2.1和6.2倍。薄层层析试验表明,呋虫胺在南京黄棕壤、江西红壤与东北黑土的Rf值分别为0.77、0.87和0.55,呋虫胺在南京黄棕壤和江西红壤中属于可移动,在东北黑土中属于中等移动。土柱淋溶试验结果显示,呋虫胺在南京黄棕壤和江西红壤淋出液中含量为总量的37.4%和65.0%,呋虫胺在东北黑土中主要集中在10.0~30.0 cm处。研究表明表明呋虫胺对地下水污染存在潜在风险性,应引起足够重视。
Studies on the Degradation and Mobility of Dinotefuran in Soil
Extensive use of dinotefuran can cause some problems such as soil and groundwater pollution, and deterioration of ecological environment. Researching the degradation characteristics and mobility of dinotefuran in soil has important significance for environment safety evaluation of dinotefuran. The degradation and mobility of dinotefuran in three kinds of soils were investigated, and the influence factors of dinotefuran degradation in soil were studied by using indoor simulating test. The results showed that the degradation rates of dinotefuran in three kinds of soils following sequence: Nanjing yellow-brown soil > Northeast China black soil > Jiangxi red soil,and the half life were 35.2, 92.4 and 154.0 days, respectively. Dinotefuran possess a medium degradation in Nanjing yellow-brown soil,and difficult degradation in Jiangxi red soil and Northeast China black soil. The decay of dinotefuran was accelerated with the moisture of soil elevating, dinotefuran decay was decreased with 80% moisture treatments because microbial organisms growth was inhibited. When the microbial organisms and organic matter are present in soil, the degradations of dinotefuran were accelerated 2.1 and 6.2 times, respectively. The soil thin-layer chromatography (TLC) showed that theRf of dinotefuran were 0.77, 0.87 and 0.55 in Nanjing yellow-brown soil, Jiangxi red soil and Northeast China black soil, respectively. These results indicated that dinotefuran was removable in Nanjing yellow-brown soil and Jiangxi red soil, medium-mobile in Northeast China black soil. The results of soil column leaching showed that 37.4% and 65.0% dinotefuran were leached out in Nanjing yellow-brown soil and Jiangxi red soil, respectively. Dinotefuran moved mainly in a distance of 10.0~30.0 cm in Northeast China black soil. This work demonstrates that dinotefuran has potential risk for contaminating groundwater and attention should be paid to its application.

dinotefurandegradation in soilmobilityleaching

刘纪松、胡存中、陆凡、施海燕、王鸣华

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南京农业大学植物保护学院,江苏南京 210095

江苏苏科农化有限责任公司,江苏南京 210014

呋虫胺 土壤降解 移动 淋溶

江苏省研究生工作站项目

2015

生态环境学报
广东省生态环境与土壤研究所 广东省土壤学会

生态环境学报

CSTPCDCSCD北大核心
影响因子:1.608
ISSN:1674-5906
年,卷(期):2015.(6)
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