首页|Nb微合金化对Cr-Co-Ni-Mo系超高强度不锈钢腐蚀疲劳性能的影响

Nb微合金化对Cr-Co-Ni-Mo系超高强度不锈钢腐蚀疲劳性能的影响

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为探讨超高强度不锈钢的应力腐蚀开裂行为,采用Cr-Co-Ni-Mo系超高强度不锈钢为研究对象,利用OM、XRD、TEM等测试手段,结合腐蚀疲劳试验,研究了Nb微合金化对Cr-Co-Ni-Mo系超高强度不锈钢腐蚀疲劳性能的影响.结果表明,试验钢在3.5%NaCl溶液中具有一定的应力腐蚀敏感性,其应力腐蚀开裂机理为氢致开裂和阳极溶解的混合机制.Nb微合金化提高了钢的腐蚀疲劳性能,钢中添加0.11%的Nb后,钢的腐蚀疲劳强度由440 MPa提高至495 MPa,其主要原因是,Nb微合金化可以细化钢的晶粒尺寸,促进钢中不可逆氢陷阱NbC的析出,增加了钢中原奥氏体晶界总量、小角晶界所占比例、Σ3晶界数量、奥氏体体积分数等.
Effect of Niobium Alloying on the Corrosion Fatigue Properties of the Cr-Co-Ni-Mo Series of Ultra-high Strength Stainless Steels
In order to investigate the stress corrosion cracking behavior of ultra-high strength stainless steel,the influence of Nb microalloying on the corrosion fatigue properties of Cr-Co-Ni-Mo series ultra-high strength stainless steel was studied by OM,XRD,TEM and other testing methods in combination with corrosion fatigue test.The results show that the steel has stress corrosion sensitivity in 3.5%NaCl solution,and the stress corrosion cracking mechanism of the steel was a mixed mechanism involving hydrogen embrittlement and anodic dissolution.Niobium alloying improved the corrosion fa-tigue performance of the steel,that is,the corrosion fatigue strength of steel increases from 440 MPa to 495 MPa after add-ing 0.11%Nb.The main reason is that niobium alloying refined the grain size of steel,promoted the precipitation of irre-versible hydrogen trap of NbC in steel,and increased the amount of prior austenite grain boundaries,the proportion of low-angle grain boundaries,the number of Σ3 grain boundaries,and the volume fraction of austenite in steel.

Ultra-high Strength Stainless SteelsErosion FatigueMechanism of Stress Corrosion CrackingNbCAus-tenite

田帅、张雪凌、刘振宝、王晓辉、王长军、孙永庆、杨志勇、齐越

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钢铁研究总院有限公司特殊钢研究院,北京 100081

钢研纳克检测技术股份有限公司,北京 100081

抚顺特殊钢股份有限公司技术中心,抚顺 113001

超高强度不锈钢 腐蚀疲劳 应力腐蚀开裂机理 NbC 奥氏体

2024

特殊钢
中国金属学会特殊钢分会 大冶特殊钢股份有限公司

特殊钢

影响因子:0.345
ISSN:1003-8620
年,卷(期):2024.45(1)
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