首页|S44535铁素体不锈钢高温氧化行为

S44535铁素体不锈钢高温氧化行为

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为了探究稀土 La对S44535铁素体不锈钢高温氧化行为的影响,采用加速氧化对添加0.26%La的S44535钢在800、900、1 000 ℃下的静态空气中进行高温氧化研究.采用恒温氧化法对比S44535铁素体不锈钢在三种温度下的氧化动力学曲线,用扫描电镜(SEM)、能谱分析仪(EDS)和X射线衍射(XRD)对钢的氧化层进行表征分析,探究了稀土 La对铁素体不锈钢高温抗氧化性能的影响.结果表明,氧化产物主要为Cr2O3和MnCr2O4,随着温度的升高,表面氧化膜增厚且更加致密,其外层富含Mn,内层富含Cr,说明稀土改变了氧化膜的生长方式,且呈现出较为优异的高温抗氧化性能.
High Temperature Oxidation Behavior of S44535 Ferritic Stainless Steel
In order to explore the effect of rare earth La on the high-temperature oxidation behavior of S44535 ferritic stain-less steel,accelerated oxidation was used to study the high-temperature oxidation of S44535 steel added with 0.26 wt.%La in static air at 800℃,900 ℃and 1 000 ℃.In this paper,the oxidation kinetic curves of S44535 ferritic stainless steel at three temperatures were compared by constant temperature oxidation method,and the oxide layer of steel was character-ized by scanning electron microscopy(SEM),energy spectroscopy analyzer(EDS)and X-ray diffraction(XRD),and the effect of rare earth La on the high-temperature oxidation resistance of ferritic stainless steel was explored.The results showed that the oxidation products were mainly Cr2O3 and MnCr2O4,and with the increase of temperature,the surface ox-ide film thickened and became denser,and its outer layer was rich in Mn,and the inner layer was rich in Cr,indicating that rare earths changed the growth direction of the oxide film,and showed excellent high temperature oxidation resistance performance.

Solid Oxide Fuel CellsFerritic Stainless SteelHigh Temperature OxidationOxidation KineticsRare Earth La

曹小强、贾建文、岳习文、胡群昆、卫英慧、侯利锋

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太原理工大学材料科学与工程学院,太原 030024

山西省金属材料腐蚀与防护工程技术研究中心,太原 030024

固体氧化物燃料电池 铁素体不锈钢 高温氧化 氧化动力学 稀土 La

山西省科技创新人才团队专项计划山西浙大新材料与化工研究院项目吕梁市引进高层次科技人才重点研发项目太原市揭榜挂帅项目

2022040510010042021SX-FR006Rc2020-109

2024

特殊钢
中国金属学会特殊钢分会 大冶特殊钢股份有限公司

特殊钢

影响因子:0.345
ISSN:1003-8620
年,卷(期):2024.45(2)
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