特殊钢2024,Vol.45Issue(6) :37-47.DOI:10.20057/j.1003-8620.2024-00138

稀土Ce对20MnTiB冷镦钢中夹杂物演变的影响

Effect of Rare Earth Ce on the Evolution of Inclusions in 20MnTiB Cold Heading Steel

郑安民 樊轩宇 黄增鑫 毛旺旺 于彦冲 张金玲 王社斌
特殊钢2024,Vol.45Issue(6) :37-47.DOI:10.20057/j.1003-8620.2024-00138

稀土Ce对20MnTiB冷镦钢中夹杂物演变的影响

Effect of Rare Earth Ce on the Evolution of Inclusions in 20MnTiB Cold Heading Steel

郑安民 1樊轩宇 2黄增鑫 1毛旺旺 2于彦冲 2张金玲 2王社斌2
扫码查看

作者信息

  • 1. 山西新泰钢铁有限公司,介休 032000
  • 2. 太原理工大学材料科学与工程学院,太原 030024
  • 折叠

摘要

工业化实验生产不同稀土(Ce)含量的20MnTiB冷镦钢,通过实验观察和热力学计算,研究了在Ca处理的基础上,Ce对20MnTiB冷镦钢生产过程中夹杂物演变的影响.结果表明,经Ce处理后,大尺寸类球状Al2O3·MgO·CaO·CaS夹杂物被变质分解为1 μm左右类球状的CeAlO3·MgO·CaO·CaS夹杂物,2 μm左右不规则状的该类型夹杂物被变质球化.热轧后,0Ce试样盘条中夹杂物沿轧制方向拉长,夹杂物尺寸更大,形状愈发不规则,此外,还发现长条状MnS夹杂物.而在27Ce试样中,经Ce处理后w[S]降低40%,抑制了凝固过程中MnS夹杂物的形成,且经轧制后,盘条中夹杂物小尺寸、类球状的特性并未发生改变.热力学计算结果与实验结果相吻合.Ce处理后,大尺寸、不规则夹杂物的变质分解、小尺寸、不规则状夹杂物的变质球化以及MnS夹杂物的消失,避免了在冷镦过程中由于夹杂物不规则形貌引起的应力集中,从而有利于实验钢冷镦性能的提升.研究结果可为进一步开发新型稀土微合金化冷镦钢提供技术和理论支撑.

Abstract

Industrialized tests were carried out to produce 20MnTiB cold heading steel with different rare earth(Ce)con-tents,the effect of Ce on the evolution of inclusions during the production of 20MnTiB cold heading steel based on Ca treat-ment was investigated through experimental observations and thermodynamic calculations.The results show that after Ce treatment,the large-size spheroidal Al2O3-MgO-CaO-CaS inclusions were metamorphosed and decomposed into about 1 μm spheroidal CeAlO3-MgO-CaO-CaS inclusions,and irregular inclusions of this type around 2 μm were metamorphosed and sphericalized.After hot rolling,the inclusions in the 0Ce specimen wire rod elongated along the rolling direction,the in-clusions were larger in size and more irregular in shape,in addition,long strips of MnS inclusions were found.However,in the 27Ce specimen,the S element content was reduced by 40% after Ce treatment,which inhibited the formation of MnS inclusions during the solidification process,and the small-sized,spherical-like characteristics of the inclusions in the wire rods did not change after rolling.The thermodynamic calculations are in agreement with the experimental results.Af-ter Ce treatment,the metamorphic decomposition of large-sized and irregular inclusions,the metamorphic spheroidization of small-sized and irregular inclusions,and the disappearance of MnS inclusions avoided the stress concentration caused by the irregular morphology of inclusions in the process of cold heading,which is conducive to the enhancement of the cold heading performance of the test steel and the reduction of the possibility of cold heading cracking.The results can provide technical and theoretical support for the further development of new rare earth microalloyed cold heading steels.

关键词

20MnTiB冷镦钢/Ca处理/Ce处理/夹杂物演变/热力学计算

Key words

20MnTiB Cold Heading Steel/Ca Treatment/Ce Treatment/Inclusion Evolution/Thermodynamic Calcula-tion

引用本文复制引用

基金项目

国家自然科学基金(52004180)

中国博士后科学基金(2020M683706XB)

山西省回国留学人员科研资助项目(2023-080)

出版年

2024
特殊钢
中国金属学会特殊钢分会 大冶特殊钢股份有限公司

特殊钢

影响因子:0.345
ISSN:1003-8620
参考文献量7
段落导航相关论文