首页|腐殖酸和富里酸对碱式硫酸镁水泥性能的影响

腐殖酸和富里酸对碱式硫酸镁水泥性能的影响

Effect of Humic Acid and Fulvic Acid on Properties of Basic Magnesium Sulfate Cement

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讨论了腐殖酸和富里酸在不同掺量下对碱式硫酸镁水泥的影响.研究结果表明,随着腐殖酸和富里酸掺量的增加,水泥基体的流动性逐渐增强,初凝和终凝时间相对延长.此外,腐殖酸和富里酸在较低掺量下对水泥的强度影响较小.具体而言,当腐殖酸掺量在0.3%和0.5%之间时,抗压抗折强度逐渐增加;然而,当掺量达到0.7%、0.9%和1.1%时,强度则呈逐渐降低的趋势.相比之下,富里酸在0.3%掺量以下时,抗压抗折强度呈上升趋势,但掺量在0.5%及以上时,强度逐渐减小.通过对微观结构的观察,发现在0.5%的腐殖酸和富里酸掺量下,水泥基体密实,孔隙较小,颗粒间排列相对有序;而在1.1%的腐殖酸掺量下,氧化镁颗粒减少,裂缝增多,颗粒之间相对较松散.总体而言,两种酸对碱式硫酸镁水泥的影响主要体现在对5·1·7相的抑制,导致碳酸镁含量上升,从而引起水泥基体的劣化.
This study explores the influence of different concentrations of humic acid and fulvic acid on basic magnesi-um sulfate cement.The results indicate that an increase in the concentration of humic acid and fulvic acid enhances the flu-idity of the cement matrix.Setting times,both initial and final,show improvement.Humic and fulvic acids have a low effect on the strength of cement at lower dosages small.Compressive and flexural strength exhibit a rising trend at humic acid concentrations of 0.3%and up to 0.5%.However,at concentrations of 0.7%,0.9%,and 1.1%,the strength decrea-ses.Concerning fulvic acid,the compressive and flexural strength increase at concentrations of 0.3%and up to 0.5%,but beyond the 0.5%threshold,there is a continuous decrease in strength.Microstructural analysis shows that at a concentra-tion of 0.5%,the matrix is dense,with small pore sizes and relatively orderly particle arrangements.Conversely,at a con-centration of 1.1%humic acid,there are fewer magnesium oxide particles,an increased number of cracks,and a relatively loose particle arrangement.The influence of the two acids on basic magnesium sulfate cement is mainly reflected in the in-hibition of the 5·1·7 phase,leading to an increase in magnesium carbonate content and the degradation of the cement matrix.

basic magnesium sulfate cementhumic acidfulvic acidstrengthmicroscopic testing

舒莉、孙永涛、肖绍彬、徐迅、刘倩、周廷柱、袁藩

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西南科技大学土木工程与建筑学院,绵阳 621010

四川科宏石油天然气工程有限公司,成都 610051

碱式硫酸镁水泥 腐殖酸 富里酸 强度 微观测试

四川省科技厅省院省校合作项目

2023YFSY0019

2024

武汉理工大学学报
武汉理工大学

武汉理工大学学报

影响因子:0.649
ISSN:1671-4431
年,卷(期):2024.46(1)
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