Improving the corrosion and frost resistance of concrete by using supermolecular reactive agents,studied the effects of supermolecular reactive agents on the chloride ion migration coefficient of concrete,compressive strength corro-sion resistance coefficient and relative dynamic modulus of elasticity of concrete after freeze-thaw cycles,and the morphol-ogy of hydration products at different ages was observed through scanning electron microscopy.The results showed that the chloride ion migration coefficient of C40 concrete mixed with 2%supramolecular active agent decreased by 78.0%af-ter 28 days,the compressive strength and corrosion resistance coefficient of KS150 concrete increased by 32.1%,and the relative dynamic elastic modulus of F150 concrete increased by 85.7%.