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组织变化对HDR双相不锈钢点蚀性能的影响

Effect of Microstructure Evolution on Corrosion Resistance of HDR Duplex Stainless Steel

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通过1 100~1 400 ℃固溶处理制备了具有不同基体组成相比例的HDR双相不锈钢试样,利用电化学测试技术,结合电子扫描电镜(SEM)和能谱仪(EDS),分析点蚀形貌和组织成分变化.结果显示:HDR双相不锈钢经过1 100~1 400 ℃热处理后,改变了主要合金元素(Cr,Mo,Mn,Ni,N)在铁素体a相和奥氏体γ相中的分配以及两相在整个组织中占比,铁素体a相占比由原来的50.3%增加到93.2%;1 100 ℃点蚀坑最小,耐点蚀能力最好;点蚀电位先减小后增大再减小波动变化,1 250 ℃处为波动点,此时弱相从铁素体组织转变为奥氏体组织;两相的微区电化学活性及两相间的电位梯度(△E)越大,点蚀越严重;与原始试样比,经热处理后的HDR耐点蚀能力相对较差.
The different matrix volume ratio of ferrite to austenite were prepared of HDR duplex stainless steels by so-lution treatment at 1 100~1 400 ℃.Microelectrochemical and Micro-scan vibration technology(SVET)were used for tes-ting,Combined with scanning electron microscopy(SEM)and Energy Dispersive Spectrometer(EDS)was used to ana-lyze the changes in tissue composition and the distribution characteristics of elements.The results showed that after solu-tion treatment at 1 100~1 400 ℃,the main alloying elements(Cr,Mo,Mn,Ni,N)of HDR duplex stainless steel were re-distributed between ferrite and austenite,changing the distribution of alloying elements in dual phase and the proportion of the dual phase in the entire structure.The proportion of ferrite has increased from 50.3%to 93.2%,and the HDR an-nealed at 1 100 ℃ has the smallest pitting pits and the best resistance to pitting.The pitting potential first decreases,then increases,and then decreases in fluctuation,and the fluctuation point is at 1 250 ℃,while the weak phase transforms from ferrite structure to austenite structure.The greater the micro electrochemical activity and the potential gradient(△E)of the dual phase,the more severe the pitting.However,compared to the original sample,and the worse resistance were oc-cured for the samples after solution treatment.

duplex stainless steelmicrostructure evolutionpittingcorrosion resistant

林育锋、李竹影、刘信、王晓强、张振海

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海军工程大学舰船与海洋学院,武汉 430033

双相不锈钢 组织变化 点蚀 耐蚀性

2024

武汉理工大学学报
武汉理工大学

武汉理工大学学报

影响因子:0.649
ISSN:1671-4431
年,卷(期):2024.46(1)
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