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酸性水溶液中铀的离子浮选分离

Separation of Uranium from Acid Aqueous Solution by Ionic Flotation

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开展了离子浮选法分离酸性水溶液中铀的试验研究.结果表明,采用十六烷基三甲基溴化铵作为捕收剂及起泡剂,随着溶液pH值从3升高到7,铀的去除率先增加后减少,且Na2CO3的添加对铀的去除率有显著的提高.在pH值大于5时,铀酰离子和碳酸根离子开始转变为UO2(CO3)22-及UO2(CO3)43-,而这些络合阴离子可与溶液中的CTA+相互作用.使用阳离子活性剂作为捕收剂,可防止难形成络合阴离子的其它金属离子混入,有利于提高溶液中铀分离的选择性.
The separation of uranium from acid aqueous solution by ion flotation was studied in this work.Cationic sur-factant cetyltrimethyl ammonium bromide(CTAB)was used as collector and foaming agent.The results show that the re-moval of uranium increases first and then decreases as the pH value of the solution increases from 3 to 7.It is found that the addition of Na2CO3 has a significant effect on the removal rate of uranium under acidic conditions.It is believed that with the addition of carbonate ions,uranyl ions begin to transform into UO2(CO3)22-and UO2(CO3)34-under the condi-tion of pH value greater than 5.These complex anions can interact with CTA+in solution.The cationic active agent as collector can prevent other metal ions which are difficult to form complex anions from mixing,it is beneficial to improve the selectivity of uranium separation in solution.Thus,cationic collector based ion flotation method has great application.

ion flotationuranium containing wastewatercationic collectorflotation kinetics

胡鹏飞、李成哲、林观清、郭兆佳、莫祖丽

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南华大学资源环境与安全工程学院,衡阳 421001

离子浮选 含铀废水 阳离子捕收剂 浮选动力学

湖南省大学生创新创业训练计划湖南省教育厅科学研究一般项目

S20221055533021C0279

2024

武汉理工大学学报
武汉理工大学

武汉理工大学学报

影响因子:0.649
ISSN:1671-4431
年,卷(期):2024.46(1)
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