首页|掺杂时间对水热法制备氮掺杂还原氧化石墨烯的影响研究

掺杂时间对水热法制备氮掺杂还原氧化石墨烯的影响研究

Hydrothermal Preparation of Nitrogen-doped Reduced Graphene Oxide and Its Properties as a Function of Doping Time

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以氨水为氮源,探究了水热反应时间不同情况下氮掺杂还原氧化石墨烯(NrGO)结构和性能的影响.采用扫描电镜(SEM)、X射线衍射(XRD)、拉曼光谱分析(Raman)、X射线光电子能谱分析(XPS)、比表面积分析(BET)等测试手段对其形貌和结构进行表征.结果表明,随着氮掺杂时间的增加,NrGO的氮元素含量从7.05%增加到9.22%.氮的掺杂导致了石墨烯结构缺陷增多、微观形貌褶皱增多及导电性变好,氮键构型也表现出不同的变化趋势.
The effect of different cases of hydrothermal reaction time on the structure and properties of nitrogen-doped reduced graphene oxide(NrGO)was investigated using ammonia as a nitrogen source.Scanning electron microscopy(SEM),X-ray diffraction(XRD),Raman spectroscopy(Raman),X-ray photoelectron spectroscopy(XPS),specific sur-facearea analysis(BET),and other test methods were used to characterize the morphology and structure.The results showed that the nitrogen content of NrGO increased from 7.05%to 9.22%with the increase of nitrogen doping time.Ni-trogen doping led to an increase in structural defects,an increase in micro-morphological folds and a better electrical con-ductivity of graphene,and the nitrogen bonding configurations also showed different trends.

nitrogen-doped reduced graphene oxidegraphene oxidehydrothermal methodelectrical conductivity

刘慧平、杨懿、李云鹏、周元林、李迎军

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西南科技大学环境友好能源材料国家重点实验室,绵阳 621010

西南科技大学材料与化学学院,绵阳 621010

氮掺杂还原氧化石墨烯 氧化石墨烯 水热法 导电性

西南科技大学博士基金环境友好能源材料国家重点实验室项目

23zx715420Fksy13

2024

武汉理工大学学报
武汉理工大学

武汉理工大学学报

影响因子:0.649
ISSN:1671-4431
年,卷(期):2024.46(2)
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