首页|四硼酸钠对碱激发矿渣胶凝材料水化硬化性能的影响

四硼酸钠对碱激发矿渣胶凝材料水化硬化性能的影响

Effect of Sodium Tetraborate on the Hydrationand Hardening Properties of Alkali-activated Slag

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以四硼酸钠为缓凝剂,探究其对AAS凝结时间的调控作用,并结合水化热、微观形貌、物相组成、化学键、孔结构分析阐释了微结构演变行为,揭示了缓凝机理.结果表明:当四硼酸钠掺量为0~20%(以矿渣质量计)时,AAS初凝时间由19 min延长至377 min,终凝时间由26.5 min延长至455 min,56 d抗压强度损失率能够控制在19%以内.四硼酸钠使AAS凝胶相C-A-S-H衍射峰向大角度偏移,水化诱导期延长,凝胶孔(<10 nm)及毛细孔(10~100 nm)数量增加,孔结构粗化.其缓凝机理为:四硼酸钠在矿渣表面形成含硼络合物包覆层,阻碍参与反应离子迁移,延缓水化反应.
Sodium tetraborate is used as a retarder to investigate its role in regulating the setting time of AAS,and combined with the heat of hydration,micro-morphology,physical phase composition,chemical bonding,and pore structure analysis to explain the microstructural evolution of the behaviour of the retardation mechanism is revealed.The results show that when the dosage of sodium tetraborate is 0~20%(in terms of slag mass),the initial setting time of AAS is ex-tended from 19 min to 377 min,the final setting time is extended from 26.5 min to 455 min,and the loss rate of 56 d com-pressive strength can be controlled within 19%.Sodium tetraborate makes the C-A-S-H gel's diffraction peak of AAS shift to a large angle,the hydration induction period is prolonged,the number of gel pores(<10 nm)and capillary pores(10~100 nm)increases,and the pore structure is coarsened.The mechanism of retardation is:sodium tetraborate forms a boron complex coating layer on the slag surface,hindering the migration of ions involved in the reaction and delaying the hydration reaction.

alkali-activated slagwater glasssodium tetraboratesetting timecompressive strength

谭高明、谷家行、吴博、刘志、徐健康、张全涛、马雪

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西南科技大学材料与化学学院,绵阳 621010

碱激发矿渣 水玻璃 四硼酸钠 凝结时间 抗压强度

四川省自然科学基金面上基金西南科技大学国家级大学生创新创业训练计划

24NSFSC1289202310619020

2024

武汉理工大学学报
武汉理工大学

武汉理工大学学报

影响因子:0.649
ISSN:1671-4431
年,卷(期):2024.46(5)
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