首页|电解液浓度对炭基超级电容器低温性能的影响

电解液浓度对炭基超级电容器低温性能的影响

Influence of Electrolyte Concentration on the Low-temperature Performance of Carbon-based Supercapacitors

扫码查看
通过研究一系列LiCl溶液的凝固点、电导率随温度的变化和对超级电容器电化学性能的影响.结果表明LiCl电解液的凝固过程和凝固点与浓度密切相关.不同于其他电解液,发现冷冻的LiCl溶液在-60 ℃时仍然具有0.413 mS/cm的离子电导率,以其为电解液的超级电容器可以正常工作.此外,6.5 mol/L LiCl电解液在-60 ℃时为纯液相,具有2.44 mS/cm的最大电导率.其容量与室温相比仍保留了 46.27%,且具有较好的充放电性能.
By studying the freezing point of a series of LiCl solutions,the change of conductivity with temperature and the influence on the electrochemical performance of supercapacitors.The results show that the freezing process and freez-ing point of LiCl electrolyte are closely related to the concentration.Compared with other electrolytes,we found that the frozen LiCl solution still has an ionic conductivity of 0.413 mS/cm at-60 ℃,and the supercapacitor can work normally using it as electrolyte.In addition,the 6.5 mol/L LiCl electrolyte is a pure liquid phase at-60 ℃,with a maximum con-ductivity of 2.44 mS/cm.The capacity retains 46.27%compared with room temperature,and has good charge and dis-charge performance.

supercapacitorsLiClelectrolytes concentrationlow temperature performance

赵玄烨、王洪雷、古丽齐热·图尔荪、王玉龙、何创创、庞锦标、杨昌平

展开 >

太原科技大学材料科学与工程学院,太原 030024

太原科技大学化学工程与技术学院,太原 030024

贵州振华电子信息产业技术研究有限公司,贵阳 550018

超级电容器 LiCl 电解液浓度 低温性能

&&

黔科合支撑[2022]一般056

2024

武汉理工大学学报
武汉理工大学

武汉理工大学学报

影响因子:0.649
ISSN:1671-4431
年,卷(期):2024.46(5)
  • 1