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锌溴电池电解液及电极材料研究进展

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锌溴电池因其低成本、长寿命的特点而适用于分布式储能及户用储能领域.本文对锌溴电池的电池结构、电解液和电极材料等方面的研究内容进行了较全面的综述.重点分析了不同电池结构的优劣,详细比较了不同电解液添加剂以及不同电极材料在改善电解液电导率、抑制锌枝晶生成、减少自放电和电池充放电性能方面的差异.通过对锌溴电池的循环稳定性以及充放电效率的对比,探讨了不同电解液添加剂及电极材料在锌溴电池中规模化应用的可行性.采用静态无膜锌溴电池是克服传统锌溴液流电池体积庞大、成本高的有效手段,但现有技术仍无法完全避免其自放电过程和锌枝晶的形成,因此优化设计合理的电池结构和开发性能优异的电解液添加剂是未来静态无膜锌溴电池的主要研究方向.
Research progress in electrolyte and electrode materials for zinc-bromine batteries
Zinc-bromine batteries are suitable for distributed energy storage and household energy storage because of their low cost and long life.In this paper,the research on the battery structure,electrolyte and electrode materials of zinc-bromine batteries was comprehensively reviewed.The advantages and disadvantages of different battery structures were analyzed.The differences between electrolyte additives and electrode materials in improving electrolyte conductivity,inhibiting zinc dendrite generation,reducing self-discharge and battery charge and discharge performance were compared in detail.By comparing the cycle stability and charge-discharge efficiency of zinc-bromine batteries,the feasibility of different electrolyte additives and electrode materials in large-scale applications in zinc-bromine batteries was investigated.We propose that the use of static membrane-free zinc-bromine batteries is an effective way of overcoming some drawbacks of traditional zinc-bromine flow batteries including large volume and high cost,however,the existing technology can not completely prevent the self-discharge process and the formation of zinc dendrites.Therefore,optimizing the well-designed battery structure and developing electrolyte additives with excellent performance are the future research directions for static membrane-free zinc-bromine batteries.

zinc-bromine batteryelectrolytecathode materialanode materialmembrane

邓淏天、王学华、石胜伟、廖伟寒、李世平、徐威

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武汉工程大学材料科学与工程学院,湖北 武汉 430205

锌溴电池 电解液 正极材料 负极材料 隔膜

湖北省自然科学基金

2021CFB598

2024

武汉工程大学学报
武汉工程大学

武汉工程大学学报

影响因子:0.463
ISSN:1674-2869
年,卷(期):2024.46(1)
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