首页|SrLaLiTeO6:Dy3+,Eu3+荧光粉的制备及发光性能研究

SrLaLiTeO6:Dy3+,Eu3+荧光粉的制备及发光性能研究

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白光发光二极管(LED)的商业合成方案缺少红光成分,导致合成的白光色温较高、显色性差,因此开发性能优异的单相暖白光荧光粉成为白光LED领域研究的重要课题.以Dy3+和Eu3+为掺杂剂,SrLaLiTeO6(SLLT)为基质,采用固相反应法制备了SrLaLiTeO6:Dy3+,Eu3+无机荧光粉,并通过X射线衍射仪、荧光分光光度计和色度坐标分析荧光粉的晶体结构及光学性能.结果表明:Dy3+和Eu3+成功进入SLLT晶体,无杂质产生;SLLT:0.07Dy3+,y Eu3+荧光粉在 351 nm激发下能够同时发射蓝、黄、红光,证明了Dy3+和Eu3+之间存在能量传递,弥补了单掺Dy3+荧光粉缺乏红色发射的缺陷;Eu3+离子最佳掺杂浓度为0.05,此时的色度坐标为(0.391 9,0.380 9),色温为3 733 K,接近暖白光区域.因此,SrLaLiTeO6:Dy3+,Eu3+荧光粉是一种性能优异的暖白光LED荧光粉.
Preparation and luminescence properties of SrLaLiTeO6:Dy3+,Eu3+phosphors
The commercial synthesis scheme of white light emitting diode(LED)lacks a red light component,resulting in high color temperature and poor color rendering of the synthesized white light.Therefore,the development of single-phase warm white phosphors with excellent performance has always been an important research topic in the field of white LED.SrLaLiTeO6:Dy3+,Eu3+inorganic phosphors were prepared by a solid state reaction method with Dy3+and Eu3+as dopants and SrLaLiTeO6(SLLT)as matrix.The crystal structure and optical properties of the phosphors were analyzed by X-ray diffraction,fluorospectrophotometry and chromaticity coordinates analysis.The results show that Dy3+and Eu3+successfully enter the SLLT crystal,which does not produce impurities.SLLT:0.07Dy3+,y Eu3+phosphors can simultaneously emit blue,yellow and red light under 351 nm excitation,which proves that there is an energy transfer between Dy3+and Eu3+to make up for the lack of red emission of single-doped Dy3+phosphors.The optimum doping concentration of Eu3+ion is 0.05,where the chromaticity coordinate is(0.391 9,0.380 9),the correlated color temperature is 3 733 K,which is close to the warm white light region.Consequently,SrLaLiTeO6:Dy3+,Eu3+phosphor is an excellent warm white LED phosphor.

phosphorluminescent propertySrLaLiTeO6:Dy3+,Eu3+warm white lightsolid state reaction

龚劲松、朱齐、郑小州、夏鹏举、刘凯、徐慢、戴武斌

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武汉工程大学材料科学与工程学院,湖北 武汉 430205

荧光粉 发光性能 SrLaLiTeO6:Dy3+,Eu3+ 暖白光 固相反应

湖北省技术创新专项武汉工程大学博士启动基金武汉工程大学第十四届研究生教育创新基金

2016ACA16016QD28CX2022242

2024

武汉工程大学学报
武汉工程大学

武汉工程大学学报

影响因子:0.463
ISSN:1674-2869
年,卷(期):2024.46(3)